302937
全氟（甲基环己烷）
technical grade, 90%
别名:
十一氟(三氟甲基)环己烷, 全氟甲基环己烷
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关于此项目
线性分子式:
C6F11CF3
化学文摘社编号:
分子量:
350.05
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-573-5
Beilstein/REAXYS Number:
1915981
MDL number:
Assay:
90%
Form:
liquid
grade
technical grade
Quality Level
assay
90%
form
liquid
refractive index
n17/D 1.285 (lit.)
bp
76 °C (lit.)
density
1.787 g/mL at 25 °C (lit.)
functional group
fluoro
SMILES string
FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F
InChI
1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12
InChI key
QIROQPWSJUXOJC-UHFFFAOYSA-N
General description
氯仿和全氟（甲基环己烷）的混合物可用作“氟”双相反应的溶剂。已有研究报道了全氟（甲基环己烷）的气相结构。
Application
全氟甲基环己烷可用作：
它还可用作溶剂，研究一系列烃和碳氟化合物官能化烟酸酯的亲氟性。
- 反应物，用于通过与水中的四丁基碘化铵进行光化学反应合成全氟-2-甲基环己基-1-烯醇化物。
- 氟溶剂，用于以氟 Grubbs ′二代催化剂通过降冰片烯的开环复分解聚合 (ROMP) 合成聚降冰片烯。
它还可用作溶剂，研究一系列烃和碳氟化合物官能化烟酸酯的亲氟性。
使用全氟（甲基环己烷）作为溶剂，研究一系列烃和碳氟化合物官能化的烟酸酯的亲氟性。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
Vivian Ojogun et al.
Journal of fluorine chemistry, 131(7), 784-790 (2010-06-23)
The fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters (nicotinates) is measured from their partitioning behavior (log K(P)) in the biphasic solvent system of perfluoro(methylcyclohexane) (PFMC) and toluene. The chain length of the hydrocarbon or fluorocarbon alkyl
Stephanie S Adkins et al.
The journal of physical chemistry. B, 112(15), 4760-4769 (2008-03-28)
The technique of hydrophobic ion pairing was used to solubilize the lipase from Candida rugosa in a fluorinated solvent, perfluoromethylcyclohexane (PFMC), in complex with a perfluoropolyether (PFPE) surfactant, KDP 4606. The enzyme-surfactant complex was determined to have a hydrodynamic diameter
Development of Highly Active Ring Opening Metathesis Polymerization Catalyst Systems-A New Approach for Green Catalyst Design
Tuba R, et al.
Proceedings, 2011(1), EVO3-EVO3 (2011)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 302937-100G | 04061837595561 |
| 302937-25G | 04061837595578 |