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线性分子式:
C6F11CF3
化学文摘社编号:
分子量:
350.05
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-573-5
Beilstein/REAXYS Number:
1915981
MDL number:
Assay:
90%
Form:
liquid
InChI key
QIROQPWSJUXOJC-UHFFFAOYSA-N
InChI
1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12
SMILES string
FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F
grade
technical grade
assay
90%
form
liquid
refractive index
n17/D 1.285 (lit.)
bp
76 °C (lit.)
density
1.787 g/mL at 25 °C (lit.)
functional group
fluoro
Quality Level
General description
氯仿和全氟(甲基环己烷)的混合物可用作“氟”双相反应的溶剂。已有研究报道了全氟(甲基环己烷)的气相结构。
Application
使用全氟(甲基环己烷)作为溶剂,研究一系列烃和碳氟化合物官能化的烟酸酯的亲氟性。
全氟甲基环己烷可用作:
它还可用作溶剂,研究一系列烃和碳氟化合物官能化烟酸酯的亲氟性。
- 反应物,用于通过与水中的四丁基碘化铵进行光化学反应合成全氟-2-甲基环己基-1-烯醇化物。
- 氟溶剂,用于以氟 Grubbs ′二代催化剂通过降冰片烯的开环复分解聚合 (ROMP) 合成聚降冰片烯。
它还可用作溶剂,研究一系列烃和碳氟化合物官能化烟酸酯的亲氟性。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
Vivian Ojogun et al.
Journal of fluorine chemistry, 131(7), 784-790 (2010-06-23)
The fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters (nicotinates) is measured from their partitioning behavior (log K(P)) in the biphasic solvent system of perfluoro(methylcyclohexane) (PFMC) and toluene. The chain length of the hydrocarbon or fluorocarbon alkyl
Functionalization of saturated fluorocarbons with and without light
Chen X and Lemal DM
Journal of Fluorine Chemistry, 127(9), 1158-1167 (2006)
Development of Highly Active Ring Opening Metathesis Polymerization Catalyst Systems-A New Approach for Green Catalyst Design
Tuba R, et al.
Proceedings, 2011(1), EVO3-EVO3 (2011)
Mei-Jy Jeng et al.
Critical care medicine, 34(4), 1099-1105 (2006-02-18)
To investigate the therapeutic effects of bronchoalveolar lavage (BAL) with either diluted surfactant (SBAL) or perfluorochemical liquid (PBAL), followed by either conventional mechanical ventilation (CMV) or partial liquid ventilation (PLV), on lung injury and proinflammatory cytokine production induced by meconium
John T Gerig
Journal of the American Chemical Society, 127(25), 9277-9284 (2005-06-23)
Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions since they exist as two separate phases at low temperature but become a single phase at higher temperatures. Intermolecular nuclear Overhauser effects have been used to
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