303828
乙基氯化镁 溶液
2.0 M in THF
别名:
Chloroethylmagnesium
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关于此项目
线性分子式:
CH3CH2MgCl
化学文摘社编号:
分子量:
88.82
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3647886
产品名称
乙基氯化镁 溶液, 2.0 M in THF
InChI
1S/C2H5.ClH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1
SMILES string
CC[Mg]Cl
InChI key
ZWNJJACKPNTXHY-UHFFFAOYSA-M
form
liquid
reaction suitability
reaction type: Grignard Reaction
concentration
2.0 M in THF
density
0.978 g/mL at 25 °C
Quality Level
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Application
乙基氯化镁溶液可用于：
- 采用二氧化碳进行Cp2ZrCl2催化的烯烃的乙基羧基化生成相应的羧酸。
- 通过与1-氯环丁基对甲苯基亚砜反应制备环丁基镁卡宾体。
signalword
Danger
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 1
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Zirconocene-catalyzed sequential ethylcarboxylation of alkenes using ethylmagnesium chloride and carbon dioxide
Shao P, et al.
Chemical Communications (Cambridge, England), 51(30), 6640-6642 (2015)
Cyclobutylmagnesium Carbenoids: Generation from 1-Chlorocyclobutyl p-Tolyl Sulfoxides with Ethylmagnesium Chloride, Properties, and Some Synthetic Uses
Satoh T, et al.
Synlett, 2010(02), 286-290 (2010)
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