307874
氧化钪(III)
99.9% trace rare earth metals basis, powder
别名:
三氧化二钪, 氧化钪
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关于此项目
线性分子式:
Sc2O3
化学文摘社编号:
分子量:
137.91
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
产品名称
氧化钪(III), 99.9% trace rare earth metals basis
质量水平
方案
99.9% trace rare earth metals basis
表单
powder
反应适用性
core: scandium
reagent type: catalyst
SMILES字符串
O=[Sc]O[Sc]=O
InChI
1S/3O.2Sc
InChI key
HYXGAEYDKFCVMU-UHFFFAOYSA-N
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一般描述
氧化钪(III)是一种高熔点的稀土氧化物,可作为末端二醇脱水反应的催化剂。它还可用于制备其他钪化合物的起始物。
应用
氧化钪(III)可用作一种催化剂,以通过氨基醇脱水制备不饱和胺。它还可用作一种前体,制备三氟甲磺酸钪(III),应用于催化芳香族化合物的硝化反应。
适用于真空淀积应用
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Scandium (III) trifluoromethanesulfonate catalyzed aromatic nitration with inorganic nitrates and acetic anhydride
Kawada A, et al.
Chemical & Pharmaceutical Bulletin, 50 (2002)
Dehydration of 5-amino-1-pentanol over rare earth oxides
Ohta K, et al.
Applied Catalysis A: General, 517, 73-80 (2016)
Vapor-phase catalytic dehydration of terminal diols
Abe K, et al.
Catalysis Today, 164, 419-424 (2011)
Yu Gong et al.
The journal of physical chemistry. A, 111(45), 11572-11578 (2007-10-18)
The reactions of scandium atoms and O(2) have been reinvestigated using matrix isolation infrared spectroscopy and density functional theory calculations. A series of new oxygen-rich scandium oxide/dioxygen complexes were prepared and characterized. The ground state scandium atoms react with dioxygen
Ya-Wen Zhang et al.
The journal of physical chemistry. B, 109(39), 18324-18331 (2006-07-21)
Nanostructured scandium hydrous oxides were hydrothermally synthesized at 180 degrees C for 18 h, using NaOH, NH(4)OH, and KOH as the bases. They were characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), N2 adsorption, thermogravimetry and differential
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