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Merck
CN

317632

Sigma-Aldrich

2-甲基环戊二烯三羰基锰

liquid

别名:

MCMT, 三羰基（2-甲基环戊二烯基）锰, （甲基环戊二烯基）三羰基锰, MMT, NSC 22316, 乙基 MMT

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关于此项目

线性分子式:
C5H4CH3Mn(CO)3
CAS Number:
12108-13-3
分子量:
218.09
EC 号:
235-166-5
MDL编号:
MFCD00001426
UNSPSC代码:
12161600
PubChem化学物质编号:
24859093
NACRES:
NA.22

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Product Name

2-甲基环戊二烯三羰基锰,

蒸汽密度

>1 (vs air)

质量水平

100

蒸汽压

0.05 mmHg ( 20 °C)

表单

liquid

反应适用性

core: manganese
reagent type: catalyst

折射率

n20/D 1.584 (lit.)

沸点

232-233 °C (lit.)

mp

−1 °C (lit.)

密度

1.38 g/mL at 25 °C (lit.)

SMILES字符串

[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].C[C]1[CH][CH][CH][CH]1

InChI

1S/C6H7.3CO.Mn/c1-6-4-2-3-5-6;3*1-2;/h2-5H,1H3;;;;

InChI key

LYHJNAIHGFWRKM-UHFFFAOYSA-N

相关类别

一般描述

甲基环戊二烯基三羰基锰（MMT）通常用作汽油中的抗爆剂。它也可用作无铅汽油的添加剂。

应用

甲基环戊二烯基锰三羰基可用于掺杂 ZnSe 纳米晶体。
它也可作为反应物用于：
  • Aldol 加成反应
  • 用共轭联噻吩单元制备均-和异核混合双卡宾配合物
  • 使用成形飞秒激光脉冲的分子碎裂
  • 金属有机气相外延（MOVPE）制备 GaAs（001）上生长的 MnAs薄膜

警示用语：

Danger

危险分类

Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Irrit. 2 - STOT RE 1 Inhalation

靶器官

Lungs

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

204.8 °F - closed cup

闪点(°C)

96 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCR4245
MKCR4244
MKCP0166
MKBL1371V
MKBH5032V

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Einat Peles et al.
The world journal of biological psychiatry : the official journal of the World Federation of Societies of Biological Psychiatry, 15(8), 620-628 (2014-03-29)
Methadone maintenance treatment (MMT) patients may achieve up to a 2-week privilege of methadone take-home doses (THD), which is associated with considerable responsibility. MMT patients are characterized as having poor sleep quality and low cognitive states. We studied sleep indices
Nacéra Boudia et al.
The Science of the total environment, 366(1), 143-147 (2005-11-22)
Methylcyclopentadienyl manganese tricarbonyl (MMT) is an organic derivative of manganese (Mn), used since 1976 in Canadian gasoline as an octane enhancer. Its combustion leads to the emission of Mn particles. Several studies carried out by our research group have established
Afsaneh Nouri et al.
International journal of biological macromolecules, 109, 1219-1231 (2017-11-25)
Montmorillonite -copper oxide (MMT-CuO) nanocomposites were prepared by a facile and eco-friendly method and introduced into chitosan (Cs) matrix to enhance its optical, mechanical and antibacterial properties. The synthesized composites were characterized using diffuse reflectance spectroscopy (DRS), X-ray diffraction (XRD)
Properties of homo- and heteronuclear mixed biscarbene complexes with conjugated bithiophene units
Landman, M.; et al.
Inorgorganica Chimica Acta, 363, 705-705 (2010)
Vadim V Lozovoy et al.
The journal of physical chemistry. A, 112(17), 3789-3812 (2008-04-25)
The possibility that chemical reactions may be controlled by tailored femtosecond laser pulses has inspired recent studies that take advantage of their short pulse duration, comparable to intramolecular dynamics, and high peak intensity to fragment and ionize molecules. In this
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