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Merck
CN

317632

2-甲基环戊二烯三羰基锰

liquid

别名:

MCMT, 三羰基（2-甲基环戊二烯基）锰, （甲基环戊二烯基）三羰基锰, MMT, NSC 22316, 乙基 MMT

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关于此项目

线性分子式:
C5H4CH3Mn(CO)3
化学文摘社编号:
12108-13-3
分子量:
218.09
EC 号:
235-166-5
MDL编号:
MFCD00001426
UNSPSC代码:
12161600
PubChem化学物质编号:
24859093
NACRES:
NA.22

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产品名称

2-甲基环戊二烯三羰基锰,

蒸汽密度

>1 (vs air)

质量水平

100

蒸汽压

0.05 mmHg ( 20 °C)

表单

liquid

反应适用性

core: manganese
reagent type: catalyst

折射率

n20/D 1.584 (lit.)

沸点

232-233 °C (lit.)

mp

−1 °C (lit.)

密度

1.38 g/mL at 25 °C (lit.)

SMILES字符串

[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].C[C]1[CH][CH][CH][CH]1

InChI

1S/C6H7.3CO.Mn/c1-6-4-2-3-5-6;3*1-2;/h2-5H,1H3;;;;

InChI key

LYHJNAIHGFWRKM-UHFFFAOYSA-N

相关类别

一般描述

甲基环戊二烯基三羰基锰（MMT）通常用作汽油中的抗爆剂。它也可用作无铅汽油的添加剂。

应用

甲基环戊二烯基锰三羰基可用于掺杂 ZnSe 纳米晶体。
它也可作为反应物用于：
  • Aldol 加成反应
  • 用共轭联噻吩单元制备均-和异核混合双卡宾配合物
  • 使用成形飞秒激光脉冲的分子碎裂
  • 金属有机气相外延（MOVPE）制备 GaAs（001）上生长的 MnAs薄膜

警示用语：

Danger

危险分类

Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Irrit. 2 - STOT RE 1 Inhalation

靶器官

Lungs

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

204.8 °F - closed cup

闪点(°C)

96 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCZ7649
MKCZ5395
MKCR4245
MKCR4244
MKCP0166

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D R Lynam et al.
Neurotoxicology, 20(2-3), 145-150 (1999-07-01)
Methylcyclopentadienyl Manganese Tricarbonyl (MMT) has been used since the 1970s in the U.S. as a gasoline octane enhancer Extensive testing of the effects of MMT on regulated gaseous emissions carried out on a wide variety of automobiles showed that use
Vadim V Lozovoy et al.
The journal of physical chemistry. A, 112(17), 3789-3812 (2008-04-25)
The possibility that chemical reactions may be controlled by tailored femtosecond laser pulses has inspired recent studies that take advantage of their short pulse duration, comparable to intramolecular dynamics, and high peak intensity to fragment and ionize molecules. In this
Minfeng Zeng et al.
ACS applied materials & interfaces, 8(48), 33157-33164 (2016-12-10)
Metal nanoparticles, once supported by a suitable scaffolding material, can be used as highly efficient heterogeneous catalysts for numerous organic reactions. The challenge, though, is to mitigate the continuous loss of metals from the supporting materials as reactions proceed, so
Sébastien Bolté et al.
Journal of toxicology and environmental health. Part A, 67(6), 459-467 (2004-03-06)
Methylcyclopentadienyl manganese tricarbonyl (MMT), is an additive in gasoline, and its combustion leads to the emission of Mn particles, which increase atmospheric metal concentrations. The objective of this study was to determine the level of outdoor and indoor respirable Mn
Kinjal J Shah et al.
Journal of colloid and interface science, 529, 90-99 (2018-06-11)
A variety of quaternary ammonium salts with different carbon chain lengths were used to modify and convert montmorillonite clay to organoclays. The surface modification attributing to the wettability was investigated using various techniques. The zeta-potential values of all clays showed
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