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Merck
CN

325252

双(乙酰丙酮基)二异丙基钛酸酯

75 wt. % in isopropanol

别名:

二(乙酰丙酮基)钛酸二异丙酯 溶液, TYZOR® AA 有机钛酸盐, Ti(acac)2OiPr2

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关于此项目

线性分子式:
[(CH3)2CHO]2Ti(C5H7O2)2
化学文摘社编号:
17927-72-9
分子量:
364.26
NACRES:
NA.23
PubChem Substance ID:
24859496
UNSPSC Code:
12352103
MDL number:
MFCD00000031

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InChI

1S/2C5H8O2.2C3H7O.Ti/c2*1-4(6)3-5(2)7;2*1-3(2)4;/h2*3,6H,1-2H3;2*3H,1-2H3;/q;;2*-1;+4/p-2/b2*4-3+;;;

SMILES string

CC(C)O[Ti](OC(C)C)(O\C(C)=C\C(C)=O)O\C(C)=C\C(C)=O

InChI key

OVSGBKZKXUMMHS-VVDZMTNVSA-L

form

solution

composition

Ti, 9-10.5% gravimetric

reaction suitability

core: titanium, reagent type: catalyst

concentration

75 wt. % in isopropanol

refractive index

n20/D 1.4935

density

0.995 g/mL at 25 °C

Quality Level

200

相关类别

General description

Titanium diisopropoxide bis(acetylacetonate) is a stable, organometallic titanium precursor widely used in thin film fabrication, nanomaterials, and catalysis. Its chelating acetylacetonate ligands provide excellent control over hydrolysis, making it ideal for sol-gel and vapor-phase deposition techniques. It is also suitable for non-aqueous applications like solar energy and water treatment.

Application

Titanium diisopropoxide bis(acetylacetonate) is used as a key precursor
  • For fabricating high-quality TiO₂ electron transport layers (ETLs) in inorganic perovskite solar cells, enabling efficient charge extraction and stable device performance through solution-based processing.
  • In the dip-coating of titanium oxide (TiOx) hole-blocking layers, with thermal processing allowing control over thickness, morphology, and electrical properties across various substrates.

Legal Information

TYZOR is a registered trademark of E. I. du Pont de Nemours and Company

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Danger

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

53.6 °F - closed cup

flash_point_c

12 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCJ4083
BCCD5466
BCBW4690
BCBS2681V
BCBP9015V

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Titanium (IV) acetylacetonate xerogels for processing titania films: A thermoanalytical study.
Acik I, et al.
Journal of Thermal Analysis and Calorimetry, 97(1), 39-45 (2009)
Fabrication of Porous Titania Particles from Water-in-Oil Emulsions for the Applications of Photocatalyst.
Cho YS, et al.
Journal of Dispersion Science and Technology, 37(5), 676-686 (2016)
Michael Kulbak et al.
The journal of physical chemistry letters, 6(13), 2452-2456 (2015-08-13)
Hybrid organic-inorganic lead halide perovskite photovoltaic cells have already surpassed 20% conversion efficiency in the few years that they have been seriously studied. However, many fundamental questions still remain unanswered as to why they are so good. One of these
Monovalent Cation Doping of CH3NH3PbI3 for Efficient Perovskite Solar Cells.
Abdi-Jalebi M, et al.
Journal of Visualized Experiments, 121, e55307-e55307 (2017)
Jingqi Liu et al.
Scientific reports, 9(1), 1362-1362 (2019-02-06)
Previously, textile dye sensitised solar cells (DSSCs) woven using photovoltaic (PV) yarns have been demonstrated but there are challenges in their implementation arising from the mechanical forces in the weaving process, evaporation of the liquid electrolyte and partially shaded cells
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