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Merck
CN

326755

乙酸铜

greener alternative

98%

别名:

醋酸铜

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关于此项目

线性分子式:
Cu(CO2CH3)2
化学文摘社编号:
分子量:
181.63
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
EC Number:
205-553-3
Beilstein/REAXYS Number:
3595638
MDL number:
Assay:
98%
Form:
powder or crystals
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vapor density

6.9 (vs air)

Quality Level

assay

98%

form

powder or crystals

reaction suitability

reaction type: click chemistry

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

SMILES string

CC(=O)O[Cu]OC(C)=O

InChI

1S/2C2H4O2.Cu/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI key

OPQARKPSCNTWTJ-UHFFFAOYSA-L

General description

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了催化效率。点击此处获取更多信息。

乙酸铜又名醋酸铜,在绿色化学领域,可用作多种过程的催化剂。尤其在交叉偶联反应中可促进碳-碳键或碳-杂原子键形成,而无需添加有害试剂或溶剂。

Application

氢气还原胺化反应合成胺这种绿色方法的催化剂。

使用环保的分子氢完成铜催化的芳酮和脂酮与苯胺的还原胺化反应

醋酸铜用作催化剂:
  • 用于α-氨基酯和对甲基苯硼酸经交叉偶联反应N-芳基化为双芳基
  • 用于取代异噁唑衍生物的合成


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signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

存储类别

8B - Non-combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

does not flash

flash_point_c

does not flash

ppe

dust mask type N95 (US), Eyeshields, Gloves



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

Explore click chemistry: efficient, high-yield reactions for drug discovery, bioconjugation, and green chemistry with simple conditions and wide applications.

Explore the principles and applications of click chemistry in drug discovery, highlighting efficient reactions that streamline the synthesis of bioactive compounds.

Explore the principles and applications of click chemistry in drug discovery, highlighting efficient reactions that streamline the synthesis of bioactive compounds.

查看所有文章

N-Arylation of ?-aminoesters with p-tolylboronic acid promoted by copper (II) acetate
PYS Lam, et al.
Tetrahedron Letters, 44, 1691-1694 (2003)
An efficient synthesis of novel isoxazole bearing pyrazole derivatives via [3+ 2] heteroannulation using cupric acetate
B Audichya, et al.
Journal of Heterocyclic Chemistry, 59, 341-350 (2022)
Heather A Michaels et al.
Chemistry, an Asian journal, 6(10), 2825-2834 (2011-09-29)
Polytriazole ligands such as the widely used tris[(1-benzyl-1H-1,2,3-triazol-4-yl)methyl]amine (TBTA), are shown to assist copper(II) acetate-mediated azide-alkyne cycloaddition (AAC) reactions that involve nonchelating azides. Tris(2-{4-[(dimethylamino)methyl]-1H-1,2,3-traizol-1-yl}ethyl)amine (DTEA) outperforms TBTA in a number of reactions. The satisfactory solubility of DTEA in a wide



全球贸易项目编号

货号GTIN
326755-25G04061826716458
326755-100G04061826716441