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Merck
CN

326755

乙酸铜

greener alternative

98%

别名:

醋酸铜

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关于此项目

线性分子式:
Cu(CO2CH3)2
化学文摘社编号:
142-71-2
分子量:
181.63
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
24859620
EC Number:
205-553-3
Beilstein/REAXYS Number:
3595638
MDL number:
MFCD00008690
Assay:
98%
Form:
powder or crystals

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InChI key

OPQARKPSCNTWTJ-UHFFFAOYSA-L

InChI

1S/2C2H4O2.Cu/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

SMILES string

CC(=O)O[Cu]OC(C)=O

vapor density

6.9 (vs air)

assay

98%

form

powder or crystals

reaction suitability

reaction type: click chemistry

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

, Aligned

Quality Level

200

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相关类别

Application

氢气还原胺化反应合成胺这种绿色方法的催化剂。

使用环保的分子氢完成铜催化的芳酮和脂酮与苯胺的还原胺化反应

醋酸铜用作催化剂：
  • 用于α-氨基酯和对甲基苯硼酸经交叉偶联反应N-芳基化为双芳基
  • 用于取代异噁唑衍生物的合成

General description

我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。点击此处获取更多信息。

乙酸铜又名醋酸铜，在绿色化学领域，可用作多种过程的催化剂。尤其在交叉偶联反应中可促进碳-碳键或碳-杂原子键形成，而无需添加有害试剂或溶剂。

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

存储类别

8B - Non-combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

does not flash

flash_point_c

does not flash

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCP1278
0000496451
0000496451
0000468146
0000468146

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An efficient synthesis of novel isoxazole bearing pyrazole derivatives via [3+ 2] heteroannulation using cupric acetate
B Audichya, et al.
Journal of Heterocyclic Chemistry, 59, 341-350 (2022)
N-Arylation of ?-aminoesters with p-tolylboronic acid promoted by copper (II) acetate
PYS Lam, et al.
Tetrahedron Letters, 44, 1691-1694 (2003)
Celly M S Izumi et al.
The journal of physical chemistry. B, 109(47), 22131-22140 (2006-07-21)
This work emphasizes the important role of the synthetic parameters in the structure of the polymeric material obtained in the aniline polymerization. The polymers formed by the oxidative polymerization of aniline by copper(II) ions in acidic aqueous solution, acetonitrile/water medium
Microwave-assisted efficient copper-promoted N-arylation of amines with arylboronic acids.
Shiyu Chen et al.
Journal of combinatorial chemistry, 10(3), 358-360 (2008-04-09)
Sodeh Sadjadi et al.
Ultrasonics sonochemistry, 18(2), 480-483 (2010-09-02)
A new, convenient method for the syntheses of 2-arylbenzothiazoles is described in the presence of catalytic amounts of Cu(OAc)(2)/MCM-41 under ultrasonic irradiation. Short reaction times, easy and quick isolation of the products, reusability of the catalyst and excellent yields are
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