327638
溴代五羰基铼(I)
98%
别名:
五羰基溴铼(I), 溴代五羰基铼
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关于此项目
线性分子式:
Re(CO)5Br
化学文摘社编号:
分子量:
406.16
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
238-084-8
MDL number:
assay
98%
reaction suitability
core: rhenium, reagent type: catalyst
SMILES string
Br[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/5CO.BrH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
InChI key
NWJBOTGGBYFKEJ-UHFFFAOYSA-M
Application
用于研究三羰基环铼和二亚胺配体形成的 π-缺电子络合物，也可用于制备 [3]-二茂铁吩络合物。
用于研究三羰基环铼和二亚胺配体形成的 π-缺电子络合物。
铼-多吡啶络合物的原料，这种络合物在催化和太阳能转化中具有应用前景。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Nishiyama, Y.; Kakushou, F. et al.
Bulletin of the Chemical Society of Japan, 73, 2779-2779 (2000)
Inorganic Chemistry, 29, 2909-2909 (1990)
Tomás F Beltrán et al.
Dalton transactions (Cambridge, England : 2003), 46(28), 9036-9048 (2017-07-01)
The superbulky N-heterocyclic carbenes (NHCs) 2,6-bis(diphenylmethyl)-4-methylimidazol-2-ylidene (IDip*Me) and its 4-methoxy analogue (IDip*OMe) reacted instantaneously with carbon disulfide to afford the corresponding imidazolium-2-dithiocarboxylate zwitterions in high yields. These new dithiolate ligands were fully characterized and their coordination chemistry toward common Re(i)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 327638-1G | 04061826717011 |