Quality Level
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
1.0 M in THF
density
1.004 g/mL at 25 °C
SMILES string
Br[Mg]c1ccccc1
InChI
1S/C6H5.BrH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
InChI key
ANRQGKOBLBYXFM-UHFFFAOYSA-M
Application
苯基溴化镁（PhMgBr）溶液是一种主要用于格氏反应的有机镁试剂，该反应可作为合成（S）-2-（二苯基甲基）吡咯烷（一种用于NMR分析的手性溶剂化试剂）中的关键步骤。PhMgBr还可以与烷基氯化物进行钯催化的Grignard偶联，以良好的收率形成交叉偶联产物。
Other Notes
低于25°C条件下储存可能会导致结晶的形成。缓慢加热以重新溶解固体。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
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signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
target_organs
Central nervous system, Respiratory system
法规信息
危险化学品
此项目有
Palladium?Catalyzed Coupling of Alkyl Chlorides and Grignard Reagents.
Frisch A C, et al.
Angewandte Chemie (International Edition in English), 41(21), 4056-4059 (2002)
A short synthesis of (S)-2-(diphenylmethyl) pyrrolidine, a chiral solvating agent for NMR analysis.
Bailey D J, et al.
Tetrahedron Asymmetry, 8(1), 149-153 (1997)
Ying Li et al.
Analytica chimica acta, 884, 106-113 (2015-06-16)
A novel molecularly imprinted electrochemical sensor based on Fe3O4 nanobeads immobilized on graphene (Fe3O4-MIP@RGO) has been developed for detecting 17β-estradiol (17β-E2) in water using reversible addition fragmentation chain transfer (RAFT) polymerization technique. 17β-E2 can be detected by this electrochemical sensor
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 331376-PZ | 04061823810920 |
| 331376-100ML | 04061826727867 |
| 331376-800ML | 04061826727874 |
| 331376-4X25ML | 04065268447413 |
| 331376-50ML | 04061838126559 |