331376
苯基溴化镁 溶液
1.0 M in THF
别名:
PhMgBr溶液
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关于此项目
线性分子式:
C6H5MgBr
化学文摘社编号:
分子量:
181.31
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3588849
产品名称
苯基溴化镁 溶液, 1.0 M in THF
InChI
1S/C6H5.BrH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
SMILES string
Br[Mg]c1ccccc1
InChI key
ANRQGKOBLBYXFM-UHFFFAOYSA-M
reaction suitability
reaction type: Grignard Reaction
concentration
1.0 M in THF
density
1.004 g/mL at 25 °C
Quality Level
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Application
苯基溴化镁（PhMgBr）溶液是一种主要用于格氏反应的有机镁试剂，该反应可作为合成（S）-2-（二苯基甲基）吡咯烷（一种用于NMR分析的手性溶剂化试剂）中的关键步骤。PhMgBr还可以与烷基氯化物进行钯催化的Grignard偶联，以良好的收率形成交叉偶联产物。
Other Notes
低于25°C条件下储存可能会导致结晶的形成。缓慢加热以重新溶解固体。
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Palladium?Catalyzed Coupling of Alkyl Chlorides and Grignard Reagents.
Frisch A C, et al.
Angewandte Chemie (International Edition in English), 41(21), 4056-4059 (2002)
A short synthesis of (S)-2-(diphenylmethyl) pyrrolidine, a chiral solvating agent for NMR analysis.
Bailey D J, et al.
Tetrahedron Asymmetry, 8(1), 149-153 (1997)
Ying Li et al.
Analytica chimica acta, 884, 106-113 (2015-06-16)
A novel molecularly imprinted electrochemical sensor based on Fe3O4 nanobeads immobilized on graphene (Fe3O4-MIP@RGO) has been developed for detecting 17β-estradiol (17β-E2) in water using reversible addition fragmentation chain transfer (RAFT) polymerization technique. 17β-E2 can be detected by this electrochemical sensor
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