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Merck
CN

333239

四氟化钛

powder and chunks

别名:

四氟化钛, 氟化钛

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关于此项目

线性分子式:
TiF4
化学文摘社编号:
分子量:
123.86
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
232-017-6
MDL number:
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产品名称

四氟化钛,

InChI key

XROWMBWRMNHXMF-UHFFFAOYSA-J

InChI

1S/4FH.Ti/h4*1H;/q;;;;+4/p-4

SMILES string

F[Ti](F)(F)F

form

powder and chunks

reaction suitability

core: titanium, reagent type: catalyst

density

2.798 g/mL at 25 °C (lit.)

Quality Level

Application

作为催化剂用于:
  • 醛基双乙酸酯的化学选择性合成与脱保护
用于制备糖基氟化物 ;糖基化 ;氟醇的制备 ;在醛和亚胺中添加碳负离子。

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Annette Wiegand et al.
Archives of oral biology, 54(8), 790-795 (2009-06-02)
This study aimed to analyse and compare the protective effect of buffered (pH 3.5) and native (pH 1.2) TiF(4) in comparison to NaF solutions of same pH on dentin erosion. Bovine samples were pretreated with 1.50% TiF(4) or 2.02% NaF
Thomas R Gordon et al.
Journal of the American Chemical Society, 134(15), 6751-6761 (2012-03-27)
Control over faceting in nanocrystals (NCs) is pivotal for many applications, but most notably when investigating catalytic reactions which occur on the surfaces of nanostructures. Anatase titanium dioxide (TiO(2)) is one of the most studied photocatalysts, but the shape dependence
Annette Wiegand et al.
Archives of oral biology, 55(3), 223-228 (2010-01-20)
This in situ study aimed to analyse the impact of different tetrafluorides (TiF(4), ZrF(4) and HfF(4)) and AmF on erosion and erosion plus abrasion of enamel and dentin. Ten volunteers took part in this crossover and double-blind study performed in
Annette Wiegand et al.
Oral health & preventive dentistry, 8(2), 159-164 (2010-07-01)
The present review summarises the effects of titanium tetrafluoride (TiF(4)) on the development and progression of carious and erosive lesions. The mode of action of TiF(4) is due to the formation of an acid-stable surface layer, which provides mechanical protection
M Dündar et al.
Journal of dental research, 90(1), 93-98 (2010-10-14)
Hybrid-layer degradation occurs because of acidic properties of currently used adhesive systems. Titanium tetrafluoride couples with tooth surface, and titanium compounds are not substituted. Caffeic acid phenethyl esther inhibits endogenous matrix metalloproteinases that cause hybrid-layer degradation. It was hypothesized that

商品

Titanium dioxide applications: Semiconducting material characteristics and diverse functionalities.

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