335002
羰基二氢化三（三苯基膦）钌 (II)
可持续性特点
别名:
碳酰二氢三(三苯膦基)钌
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关于此项目
线性分子式:
[(C6H5)3P]3Ru(CO)H2
化学文摘社编号:
分子量:
919.79
MDL number:
UNSPSC Code:
12352202
PubChem Substance ID:
NACRES:
NA.22
Quality Segment
reaction suitability
core: ruthenium, reagent type: catalyst
reaction type: C-H Activation
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Sustainability features
mp
161-163 °C (lit.)
SMILES string
[RuH2].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI
1S/3C18H15P.CO.Ru.2H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h3*1-15H;;;;
InChI key
MLIYPCQSOXNTLJ-UHFFFAOYSA-N
General description
We are committed to providing greener alternatives that adhere to the 12 Principles of Green Chemistry. This versatile phosphine ligand enables efficient transition metal-catalyzed cross-coupling reactions with enhanced selectivity and reduced byproduct formation, thus aligns with Green Chemistry principle "Catalysis". Click here for more information.
Application
- 用于将 1,4-烷二醇转化为吡咯的催化剂
- 用于将伯醇氧化成甲酯的催化剂
- 用于将肟重排成酰胺的催化剂
- 通过定向 C-H 活化进行 C-C 偶联的催化剂
- 环戊烷环化的催化剂
警示词
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
存储类别
11 - Combustible Solids
怎么回事？
WGK 3
闪点 (F)
Not applicable
闪点 (°C)
Not applicable
PPE（个人防护设备）
dust mask type N95 (US), Eyeshields, Gloves