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线性分子式:
[(C6H5)3P]4RuH2
化学文摘社编号:
分子量:
1156.26
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
二氢四(三苯基膦)钌 (II),
SMILES string
[RuH2].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12
InChI key
RXFATFKBDIQXLS-UHFFFAOYSA-N
InChI
1S/4C18H15P.Ru.2H/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h4*1-15H;;;
form
powder
reaction suitability
core: ruthenium
reagent type: catalyst
mp
181-183 °C (lit.)
Quality Level
Application
Catalyst for hydration of nitriles, isomerization of alkynes,Knoevenagel reactions and conjugate additions, and transferhydrogenation
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Murahashi, S-I.; Sasao, S. et al.
The Journal of Organic Chemistry, 57, 2521-2521 (1992)
Ma, D.; Lu, X.
Tetrahedron Letters, 30, 843-843 (1989)
Naota, T.; Taki, H. et al.
Journal of the American Chemical Society, 111, 5954-5954 (1989)
商品
Knoevenagel Condensation is an organic reaction named after Emil Knoevenagel. It is a classic C-C bond formation reaction and a modification of the Aldol Condensation.
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