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Merck
CN

339164

双(环戊二烯)钴(II)

别名:

Cobaltocene

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关于此项目

线性分子式:
Co(C5H5)2
化学文摘社编号:
1277-43-6
分子量:
189.12
NACRES:
NA.23
PubChem Substance ID:
24860617
UNSPSC Code:
12352103
EC Number:
215-061-0
MDL number:
MFCD00013749

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InChI key

PXFGMRZPRDJDEK-UHFFFAOYSA-N

InChI

1S/2C5H5.Co/c2*1-2-4-5-3-1;/h2*1-5H;

SMILES string

[Co].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

form

powder or crystals
solid

reaction suitability

core: cobalt

mp

176-180 °C (dec.) (lit.)

storage temp.

2-8°C

Quality Level

100

相关类别

Application

双(环戊二烯基)钴(II)可用于：
  • 作为掺杂剂制备 具有高热电转换效率的封装碳纳米管。
  • 作为 CVD 前驱体，用于制造 用于各种应用的氧化钴薄膜。
  • 作为锂基氧化还原液流电池中的氧化还原活性阳极物质， 以实现更高的能量密度和能源效率。
  • 作为甲基丙烯酸甲酯受控/“活性”自由基聚合的催化剂。

General description

双(环戊二烯基)钴(II)也称为二茂钴，是一种有机金属化合物，广泛应用于聚合物合成、钴纳米材料和氧化还原液流电池领域。

pictograms

FlameHealth hazard
GHS02,GHS08

signalword

Danger

Hazard Classifications

Carc. 2 - Flam. Sol. 2 - Muta. 2 - Resp. Sens. 1 - Skin Sens. 1

存储类别

4.1B - Flammable solid hazardous materials

wgk

WGK 3

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCZ4661
MKCX6733
MKCV9824
MKCV5206
MKCV5207

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Development of n-type cobaltocene-encapsulated carbon nanotubes with remarkable thermoelectric property
Takahiro Fukumaru, et al.
Scientific Reports, 5, 7951-7951 (2015)
Jacob M Clary et al.
Nanotechnology, 31(17), 175703-175703 (2020-01-09)
Highly dispersed cobalt atoms were deposited on porous alumina particles using atomic layer deposition (ALD) with a CoCp2/H2 chemistry at approximately 7 wt%. H2 did not completely reduce the cyclopentadienyl organic ligands bound to deposited Co atoms at ALD reaction
A high-performance all-metallocene-based, non-aqueous redox flow battery
Yu Ding, et al.
Energy & Environmental Science, 10, 491-497 (2017)
Thin films of cobalt oxide deposited on high aspect ratio supports by atomic layer deposition
Madeleine Diskus, et al
Chem. Vap. Deposition, 17, 135-140 (2011)
F Li et al.
Chemical science, 9(30), 6379-6389 (2018-10-13)
A series of NO-bound, iron-functionalized polyoxovanadate-alkoxide (FePOV-alkoxide) clusters have been synthesized, providing insight into the role of multimetallic constructs in the coordination and activation of a substrate. Upon exposure of the heterometallic cluster to NO, the vanadium-oxide metalloligand is oxidized
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