342041
全氟庚酸
≥97.0%
别名:
十三氟庚酸, 全氟庚酸
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关于此项目
线性分子式:
CF3(CF2)5CO2H
化学文摘社编号:
分子量:
364.06
UNSPSC Code:
12352200
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-798-9
Beilstein/REAXYS Number:
1808210
MDL number:
Assay:
≥97.0%
Form:
solid
InChI key
ZWBAMYVPMDSJGQ-UHFFFAOYSA-N
InChI
1S/C7HF13O2/c8-2(9,1(21)22)3(10,11)4(12,13)5(14,15)6(16,17)7(18,19)20/h(H,21,22)
SMILES string
OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
assay
≥97.0%
form
solid
refractive index
n20/D 1.306 (lit.)
bp
175 °C/742 mmHg (lit.)
mp
30 °C (lit.)
density
1.792 g/mL at 25 °C (lit.)
Quality Level
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Application
全氟庚酸作为反应剂的用途：
- 使用Ni/SiO2纳米催化剂，芳香化合物C-H键的氟烷基化反应。
- 通过Mitsunobu反应合成联苯基苯甲酸酯。
- 在氯甲酸甲酯的存在下，由β-硫醇胺合成N-全氟酰基β-硫醇酰胺。
signalword
Danger
target_organs
Liver
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
PBT - Repr. 1B - STOT RE 1 - vPvB
hcodes
N Kudo et al.
Chemico-biological interactions, 134(2), 203-216 (2001-04-20)
Elimination in urine and feces was compared between four perfluorinated fatty acids (PFCAs) with different carbon chain length. In male rats, perfluoroheptanoic acid (PFHA) was rapidly eliminated in urine with the proportion of 92% of the dose being eliminated within
Synthesis of new fluorous modular chiral ligand derivatives from amino alcohols and application in enantioselective carbon-carbon bond-forming alkylation reactions
Sehnem J, et al.
Tetrahedron Asymmetry, 21, 997-1003 (2010)
Mikhail N Khrizanforov et al.
Dalton transactions (Cambridge, England : 2003), 45(30), 11976-11982 (2016-07-08)
We have developed Ni(III)-doped silica nanoparticles ([(bpy)xNi(III)]@SiO2) as a recyclable, low-leaching, and efficient oxidative functionalization nanocatalyst for aromatic C-H bonds. The catalyst is obtained by doping the complex [(bpy)3Ni(II)] on silica nanoparticles along with its subsequent electrooxidation to [(bpy)xNi(III)] without
Bart B L Groen et al.
The Journal of clinical endocrinology and metabolism, 101(11), 3978-3988 (2016-11-05)
Skeletal muscle protein synthesis is highly responsive to food intake. It has been suggested that the postprandial increase in circulating insulin modulates the muscle protein synthetic response to feeding. The objective of the study was to investigate whether a greater
Huangfang Xu et al.
Environment international, 143, 105952-105952 (2020-07-28)
Long-chain per- and polyfluoroalkyl substances (PFASs) and their short-chain alternatives have been produced and used extensively in China. However, it is unclear whether these compounds contribute to the risk of gestational diabetes mellitus (GDM) in women residing in contaminated areas.
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