361844
三(三苯基膦)氯化钴(I)
97%, powder
别名:
氯化钴 (Ph3P) 3
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关于此项目
线性分子式:
[(C6H5)3P]3CoCl
化学文摘社编号:
分子量:
881.24
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
三(三苯基膦)氯化钴(I), 97%
SMILES string
Cl[Co].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI
1S/3C18H15P.ClH.Co/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
InChI key
RHNBOEDTKLKUEB-UHFFFAOYSA-M
assay
97%
form
powder
reaction suitability
core: cobalt
reagent type: catalyst
mp
135-139 °C (dec.) (lit.)
Quality Level
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Application
化学计量还原剂，用于卤代有机分子的自由基二聚化反应。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Sharanjeet K Bagal et al.
The Journal of organic chemistry, 69(26), 9100-9108 (2004-12-22)
The biomimetic synthesis of the bisesquiterpene lactones (+/-)-biatractylolide 1 and (+/-)-biepiasterolide 2 via dimerization of the captodative stabilized radical 8 is reported. Atractylon 7 has also been shown to be a possible intermediate during the biosynthesis of biatractylolide 1, biepiasterolide
Concise total synthesis of (-)-calycanthine, (+)-chimonanthine, and (+)-folicanthine.
Mohammad Movassaghi et al.
Angewandte Chemie (International ed. in English), 46(20), 3725-3728 (2007-04-07)
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