377848
1H-苯并三唑-1-基氧三吡咯烷基六氟磷酸盐
98%, for peptide synthesis
别名:
PyBOP®
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关于此项目
线性分子式:
C18H28N6OP · PF6
化学文摘社编号:
分子量:
520.39
Beilstein:
3584612
MDL编号:
UNSPSC代码:
12352107
PubChem化学物质编号:
NACRES:
NA.22
产品名称
1H-苯并三唑-1-基氧三吡咯烷基六氟磷酸盐, 98%
方案
98%
表单
powder, crystals or chunks
反应适用性
reaction type: Coupling Reactions
mp
154-156 °C (dec.) (lit.)
应用
peptide synthesis
储存温度
2-8°C
SMILES字符串
F[P-](F)(F)(F)(F)F.C1CCN(C1)[P+](On2nnc3ccccc23)(N4CCCC4)N5CCCC5
InChI
1S/C18H28N6OP.F6P/c1-2-10-18-17(9-1)19-20-24(18)25-26(21-11-3-4-12-21,22-13-5-6-14-22)23-15-7-8-16-23;1-7(2,3,4,5)6/h1-2,9-10H,3-8,11-16H2;/q+1;-1
InChI key
VIAFLMPQBHAMLI-UHFFFAOYSA-N
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应用
BOP 偶联剂类似物，不产生致癌副产物 HMPA。
试剂用于：
匹配杂交荧光单标记寡核苷酸的合成
内分泌干扰物化学结合剂的产生
模板组装多价肽结合物的环加成
匹配杂交荧光单标记寡核苷酸的合成
内分泌干扰物化学结合剂的产生
模板组装多价肽结合物的环加成
法律信息
PyBOP is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
L. Bethge, et al.,
Organic & Biomolecular Chemistry, 8, 2437-2448 (2010)
Olga Avrutina et al.
Organic & biomolecular chemistry, 7(20), 4177-4185 (2009-10-02)
Here we describe the facile generation of tetravalent peptide conjugates via a copper(I) catalyzed azide-alkyne cycloaddition (CuAAC) using a cyclic peptide template as a versatile conjugation scaffold. This stable and rigid framework is a conformationally constrained cyclic beta-sheet decorated with
S. Figaroli, et al.,
Tetrahedron, 66, 6912-6918 (2010)
Ryan J Seelbach et al.
Macromolecular bioscience, 15(8), 1035-1044 (2015-05-07)
BMP-2 and TGF-β1 released from injectable thermoresponsive hydrogels are studied in the presence and absence of branched macromolecules bearing BMP-2 or TGF-β1 affinity binding peptides. The synthesized branched macromolecules and the gelling compositions before and after loading with either BMP-2
Alan K Jarmusch et al.
Journal of pharmaceutical and biomedical analysis, 117, 11-17 (2015-09-05)
Ergot alkaloids are mycotoxins with an array of biological effects. With this study, we investigated for the first time the application of atmospheric pressure photoionization (APPI) as an ionization method for LC-MS analysis of ergot alkaloids, and compared its performance
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