377848
1H-苯并三唑-1-基氧三吡咯烷基六氟磷酸盐
98%, for peptide synthesis
别名:
PyBOP®
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线性分子式:
C18H28N6OP · PF6
化学文摘社编号:
分子量:
520.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352107
MDL number:
Beilstein/REAXYS Number:
3584612
产品名称
1H-苯并三唑-1-基氧三吡咯烷基六氟磷酸盐, 98%
InChI key
VIAFLMPQBHAMLI-UHFFFAOYSA-N
InChI
1S/C18H28N6OP.F6P/c1-2-10-18-17(9-1)19-20-24(18)25-26(21-11-3-4-12-21,22-13-5-6-14-22)23-15-7-8-16-23;1-7(2,3,4,5)6/h1-2,9-10H,3-8,11-16H2;/q+1;-1
SMILES string
F[P-](F)(F)(F)(F)F.C1CCN(C1)[P+](On2nnc3ccccc23)(N4CCCC4)N5CCCC5
assay
98%
form
powder, crystals or chunks
reaction suitability
reaction type: Coupling Reactions
mp
154-156 °C (dec.) (lit.)
application(s)
peptide synthesis
storage temp.
2-8°C
Quality Level
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Application
BOP 偶联剂类似物，不产生致癌副产物 HMPA。
试剂用于：
匹配杂交荧光单标记寡核苷酸的合成
内分泌干扰物化学结合剂的产生
模板组装多价肽结合物的环加成
匹配杂交荧光单标记寡核苷酸的合成
内分泌干扰物化学结合剂的产生
模板组装多价肽结合物的环加成
Legal Information
PyBOP is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
S. Figaroli, et al.,
Tetrahedron, 66, 6912-6918 (2010)
L. Bethge, et al.,
Organic & Biomolecular Chemistry, 8, 2437-2448 (2010)
Olga Avrutina et al.
Organic & biomolecular chemistry, 7(20), 4177-4185 (2009-10-02)
Here we describe the facile generation of tetravalent peptide conjugates via a copper(I) catalyzed azide-alkyne cycloaddition (CuAAC) using a cyclic peptide template as a versatile conjugation scaffold. This stable and rigid framework is a conformationally constrained cyclic beta-sheet decorated with
Ryan J Seelbach et al.
Macromolecular bioscience, 15(8), 1035-1044 (2015-05-07)
BMP-2 and TGF-β1 released from injectable thermoresponsive hydrogels are studied in the presence and absence of branched macromolecules bearing BMP-2 or TGF-β1 affinity binding peptides. The synthesized branched macromolecules and the gelling compositions before and after loading with either BMP-2
Alan K Jarmusch et al.
Journal of pharmaceutical and biomedical analysis, 117, 11-17 (2015-09-05)
Ergot alkaloids are mycotoxins with an array of biological effects. With this study, we investigated for the first time the application of atmospheric pressure photoionization (APPI) as an ionization method for LC-MS analysis of ergot alkaloids, and compared its performance
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