404926
三异丙氧基氧化钒(V)
别名:
VTIP, 三异丙氧基氧化钒, 氧化三异丙醇钒
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关于此项目
线性分子式:
OV(OCH(CH3)2)3
化学文摘社编号:
分子量:
244.20
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
226-997-4
MDL number:
InChI key
DSGGJXAUQHKOGQ-UHFFFAOYSA-N
InChI
1S/3C3H7O.O.V/c3*1-3(2)4;;/h3*3H,1-2H3;;/q3*-1;;+3
SMILES string
CC(C)O[V](=O)(OC(C)C)OC(C)C
form
liquid
composition
V, 20.3-21.4% titration (, by potassium permanganate)
reaction suitability
core: vanadium
reagent type: catalyst
refractive index
n20/D 1.479 (lit.)
bp
80-82 °C/2 mmHg (lit.)
density
1.035 g/mL at 25 °C (lit.)
Quality Level
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Application
钒 (V) 氧三异丙氧基化合物是一系列含有乙醚和乙酰丙酮配体的中性氧钒配合物的结构单元。钒 (V) 氧三异丙醚 (VOTP) 可直接用作掺杂 TiO2 的 V 前驱体，形成锂离子电池高性能负极。
General description
Vanadium(V) oxytriisopropoxide is a versatile liquid organometallic compound widely used as an effective solution and vapor deposition precursor, particularly in processes like chemical vapor deposition (CVD) and atomic layer deposition (ALD). Its high volatility and reactivity make it suitable for creating vanadium-based thin films, oxides, and coatings used in electronics, catalysis, and energy storage applications.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
113.0 °F - closed cup
flash_point_c
45 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Improving the electrochemical performance of anatase titanium dioxide by vanadium doping as an anode material for lithium-ion batteries.
Anh LT, et al.
Journal of Power Sources, 243, 891-898 (2013)
Feilong Jiang et al.
Inorganic chemistry, 37(21), 5439-5451 (2001-10-24)
The studies of an underexplored synthetic reagent, VO(2)(acac) (Hacac = acetylacetone) and semirational strategies for the formation of a complete series of simple vanadium(V) alkoxide clusters in alcohol-containing solvents. The neutral mono-, di-, tri-, and tetranuclear oxovanadium(V) complexes [V(2)O(2)(&mgr;-OCH(3))(2)(acac)(2)(OCH(3))(2)] (1)
Colm Glynn et al.
Nanoscale, 7(47), 20227-20237 (2015-11-18)
Devices composed of transparent materials, particularly those utilizing metal oxides, are of significant interest due to increased demand from industry for higher fidelity transparent thin film transistors, photovoltaics and a myriad of other optoelectronic devices and optics that require more
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