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404926

三异丙氧基氧化钒(V)

Name: 三异丙氧基氧化钒(V)
Brand: ALDRICH

别名:

VTIP, 三异丙氧基氧化钒, 氧化三异丙醇钒

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关于此项目

线性分子式:

OV(OCH(CH₃)₂)₃

化学文摘社编号:

5588-84-1

分子量:

244.20

NACRES:

NA.23

PubChem Substance ID:

24865281

UNSPSC Code:

12352103

EC Number:

226-997-4

MDL number:

MFCD00015017

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属性

form

liquid

Quality Level

200

composition

V, 20.3-21.4% titration (, by potassium permanganate)

reaction suitability

core: vanadium, reagent type: catalyst

refractive index

n20/D 1.479 (lit.)

bp

80-82 °C/2 mmHg (lit.)

density

1.035 g/mL at 25 °C (lit.)

SMILES string

CC(C)O[V](=O)(OC(C)C)OC(C)C

InChI

1S/3C3H7O.O.V/c3*1-3(2)4;;/h3*3H,1-2H3;;/q3*-1;;+3

InChI key

DSGGJXAUQHKOGQ-UHFFFAOYSA-N

说明

General description

Vanadium(V) oxytriisopropoxide is a versatile liquid organometallic compound widely used as an effective solution and vapor deposition precursor, particularly in processes like chemical vapor deposition (CVD) and atomic layer deposition (ALD). Its high volatility and reactivity make it suitable for creating vanadium-based thin films, oxides, and coatings used in electronics, catalysis, and energy storage applications.

Application

钒 (V) 氧三异丙氧基化合物是一系列含有乙醚和乙酰丙酮配体的中性氧钒配合物的结构单元。钒 (V) 氧三异丙醚 (VOTP) 可直接用作掺杂 TiO₂ 的 V 前驱体，形成锂离子电池高性能负极。

不对称转移氢化

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pictograms

GHS02,GHS07

signalword

Warning

hcodes

H226,H315,H319,H335

pcodes

P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

113.0 °F - closed cup

flash_point_c

45 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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Improving the electrochemical performance of anatase titanium dioxide by vanadium doping as an anode material for lithium-ion batteries.

Anh LT, et al.

Journal of Power Sources, 243, 891-898 (2013)

Stepwise Cluster Assembly Using VO(2)(acac) as a Precursor: cis-[VO(OCH(CH(3))(2))(acac)(2)], [V(2)O(2)(&mgr;-OCH(3))(2)(acac)(2)(OCH(3))(2)], [V(3)O(3){&mgr;,&mgr;-(OCH(2))(3)CCH(3)}(2)(acac)(2)(OC(2)H(5))], and [V(4)O(4)(&mgr;-O)(2)(&mgr;-OCH(3))(2)(&mgr;(3)-OCH(3))(2)(acac)(2)(OCH(3))(2)].2CH(3)CN(1).

Feilong Jiang et al.

Inorganic chemistry, 37(21), 5439-5451 (2001-10-24)

The studies of an underexplored synthetic reagent, VO(2)(acac) (Hacac = acetylacetone) and semirational strategies for the formation of a complete series of simple vanadium(V) alkoxide clusters in alcohol-containing solvents. The neutral mono-, di-, tri-, and tetranuclear oxovanadium(V) complexes [V(2)O(2)(&mgr;-OCH(3))(2)(acac)(2)(OCH(3))(2)] (1)

Solution processable broadband transparent mixed metal oxide nanofilm optical coatings via substrate diffusion doping.

Colm Glynn et al.

Nanoscale, 7(47), 20227-20237 (2015-11-18)

Devices composed of transparent materials, particularly those utilizing metal oxides, are of significant interest due to increased demand from industry for higher fidelity transparent thin film transistors, photovoltaics and a myriad of other optoelectronic devices and optics that require more

全球贸易项目编号

货号	GTIN
404926-10G	04061831987065
404926-1G	04061838139399