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Merck
CN

404926

Sigma-Aldrich

三异丙氧基氧化钒(V)

别名:

VTIP, 三异丙氧基氧化钒, 氧化三异丙醇钒

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关于此项目

线性分子式:
OV(OCH(CH3)2)3
CAS Number:
分子量:
244.20
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
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表单

liquid

质量水平

组成

V, 20.3-21.4% titration (, by potassium permanganate)

反应适用性

core: vanadium
reagent type: catalyst

折射率

n20/D 1.479 (lit.)

沸点

80-82 °C/2 mmHg (lit.)

密度

1.035 g/mL at 25 °C (lit.)

SMILES字符串

CC(C)O[V](=O)(OC(C)C)OC(C)C

InChI

1S/3C3H7O.O.V/c3*1-3(2)4;;/h3*3H,1-2H3;;/q3*-1;;+3

InChI key

DSGGJXAUQHKOGQ-UHFFFAOYSA-N

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一般描述

Vanadium(V) oxytriisopropoxide is a versatile liquid organometallic compound widely used as an effective solution and vapor deposition precursor, particularly in processes like chemical vapor deposition (CVD) and atomic layer deposition (ALD). Its high volatility and reactivity make it suitable for creating vanadium-based thin films, oxides, and coatings used in electronics, catalysis, and energy storage applications.

应用

钒 (V) 氧三异丙氧基化合物是一系列含有乙醚和乙酰丙酮配体的中性氧钒配合物的结构单元。钒 (V) 氧三异丙醚 (VOTP) 可直接用作掺杂 TiO2 的 V 前驱体,形成锂离子电池高性能负极。

象形图

FlameExclamation mark

警示用语:

Warning

危险分类

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

113.0 °F - closed cup

闪点(°C)

45 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Improving the electrochemical performance of anatase titanium dioxide by vanadium doping as an anode material for lithium-ion batteries.
Anh LT, et al.
Journal of Power Sources, 243, 891-898 (2013)
Feilong Jiang et al.
Inorganic chemistry, 37(21), 5439-5451 (2001-10-24)
The studies of an underexplored synthetic reagent, VO(2)(acac) (Hacac = acetylacetone) and semirational strategies for the formation of a complete series of simple vanadium(V) alkoxide clusters in alcohol-containing solvents. The neutral mono-, di-, tri-, and tetranuclear oxovanadium(V) complexes [V(2)O(2)(&mgr;-OCH(3))(2)(acac)(2)(OCH(3))(2)] (1)
Colm Glynn et al.
Nanoscale, 7(47), 20227-20237 (2015-11-18)
Devices composed of transparent materials, particularly those utilizing metal oxides, are of significant interest due to increased demand from industry for higher fidelity transparent thin film transistors, photovoltaics and a myriad of other optoelectronic devices and optics that require more

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