407240
三氟甲烷磺酸铜与苯的络合物
90%, technical grade, powder
别名:
三氟甲烷磺酸铜盐苯络合物, 三氟甲烷磺酸铜苯络合物, 三氟甲磺酸铜苯络合物
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关于此项目
线性分子式:
(CF3SO3Cu)2 · C6H6
化学文摘社编号:
分子量:
503.34
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
255-686-6
MDL number:
产品名称
三氟甲烷磺酸铜与苯的络合物, technical grade, 90%
InChI key
GNXZWVVAAMVOJY-UHFFFAOYSA-L
InChI
1S/C6H6.2CHF3O3S.2Cu/c1-2-4-6-5-3-1;2*2-1(3,4)8(5,6)7;;/h1-6H;2*(H,5,6,7);;/q;;;2*+1/p-2
SMILES string
[Cu+].[Cu+].c1ccccc1.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
grade
technical grade
assay
90%
form
powder
reaction suitability
core: copper, reagent type: catalyst
mp
160 °C (dec.) (lit.)
Quality Level
Application
三氟甲磺酸铜(I)苯络合物可用作以下反应的催化剂：
它还可与基于氨基酸的手性膦配体结合使用，催化烷基锌与无环α,β-不饱和酮的不对称共轭加成，以高产率和优异的对映选择性合成β-烷基羰基。
- 通过形成羧酸铜(I)中间体，合成烯醇酯。
- 环状烯烃的对映选择性烯丙基氧化。
- 通过形成磺酰胺基自由基，由N-烯基、炔基和烷基N-苯甲酰氧基磺酰胺制备2,5-二取代的吡咯烷衍生物。
它还可与基于氨基酸的手性膦配体结合使用，催化烷基锌与无环α,β-不饱和酮的不对称共轭加成，以高产率和优异的对映选择性合成β-烷基羰基。
signalword
Warning
hcodes
Hazard Classifications
Flam. Sol. 2
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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