表单
liquid
质量水平
反应适用性
core: lithium
浓度
1.0 M in methanol
沸点
64.6 °C
密度
0.817 g/mL at 25 °C
SMILES字符串
[Li+].C[O-]
InChI
1S/CH3O.Li/c1-2;/h1H3;/q-1;+1
InChI key
JILPJDVXYVTZDQ-UHFFFAOYSA-N
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一般描述
Lithium methoxide solution, also known as lithium methylate, is an organolithium compound supplied as a colorless solution in methanol. It is highly soluble in polar solvents, making it suitable for solution-based applications. It serves as a strong base in organic reactions and is used in the production of polymers and specialty chemicals.
应用
Lithium methoxide can be used as
- A lithium source in the sol-gel synthesis of a Li₂O–ZrO₂ (LZO) coating for LiNi₀.₉Co₀.₀₅Mn₀.₀₅O₂ (NCM) cathode material, enabling the formation of a uniform, amorphous LZO layer that enhances the cathode′s stability and performance in lithium-ion batteries.
- A catalyst-activating additive to generate the active zirconium hydride species required for the selective hydrosilylation of alkenes using zirconocene dichloride.
- A lithium precursor in a sol-gel synthesis method to produce high-purity γ-LiAlO₂ ceramic powders at relatively low calcination temperatures
特点和优势
Lithium methoxide solution in methanol is significant in several applications due to its strong basicity and reactivity. Its solubility in methanol allows for easy handling and mixing with other reactants, facilitating reactions in a liquid medium.
警示用语:
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Self-heat. 1 - Skin Corr. 1B - STOT SE 1
靶器官
Eyes
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 2
闪点(°F)
51.8 °F - closed cup
闪点(°C)
11 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles
法规信息
危险化学品
此项目有
Ali, A.F. et al.
Journal of Materials Research, 14, 1510-1510 (1999)
商品
Few Monolayer Atomic Layer Deposition (ALD) on Surfaces and Interfaces for Energy Applications
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