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Merck
CN

408794

Sigma-Aldrich

甲醇锂 溶液

1.0 M in methanol

别名:

甲氧基锂

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关于此项目

线性分子式:
CH3OLi
化学文摘社编号:
分子量:
37.97
Beilstein:
3552389
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
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表单

liquid

质量水平

反应适用性

core: lithium

浓度

1.0 M in methanol

沸点

64.6 °C

密度

0.817 g/mL at 25 °C

SMILES字符串

[Li+].C[O-]

InChI

1S/CH3O.Li/c1-2;/h1H3;/q-1;+1

InChI key

JILPJDVXYVTZDQ-UHFFFAOYSA-N

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一般描述

Lithium methoxide solution, also known as lithium methylate, is an organolithium compound supplied as a colorless solution in methanol. It is highly soluble in polar solvents, making it suitable for solution-based applications. It serves as a strong base in organic reactions and is used in the production of polymers and specialty chemicals.

应用

Lithium methoxide can be used as
  • A lithium source in the sol-gel synthesis of a LiO–ZrO (LZO) coating for LiNi₀.₉Co₀.₀₅Mn₀.₀₅O (NCM) cathode material, enabling the formation of a uniform, amorphous LZO layer that enhances the cathode′s stability and performance in lithium-ion batteries.
  • A catalyst-activating additive to generate the active zirconium hydride species required for the selective hydrosilylation of alkenes using zirconocene dichloride.
  • A lithium precursor in a sol-gel synthesis method to produce high-purity γ-LiAlOceramic powders at relatively low calcination temperatures

特点和优势

Lithium methoxide solution in methanol is significant in several applications due to its strong basicity and reactivity. Its solubility in methanol allows for easy handling and mixing with other reactants, facilitating reactions in a liquid medium.

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Self-heat. 1 - Skin Corr. 1B - STOT SE 1

靶器官

Eyes

储存分类代码

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 2

闪点(°F)

51.8 °F - closed cup

闪点(°C)

11 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Ali, A.F. et al.
Journal of Materials Research, 14, 1510-1510 (1999)

商品

Few Monolayer Atomic Layer Deposition (ALD) on Surfaces and Interfaces for Energy Applications

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