InChI
1S/C12H28Ge/c1-4-7-10-13(11-8-5-2)12-9-6-3/h13H,4-12H2,1-3H3
SMILES string
CCCC[GeH](CCCC)CCCC
InChI key
KTSWILXIWHVQLR-UHFFFAOYSA-N
assay
99%
form
liquid
reaction suitability
core: germanium, reagent type: reductant
refractive index
n20/D 1.45 (lit.)
bp
123 °C/20 mmHg (lit.)
density
0.949 g/mL at 25 °C (lit.)
Quality Level
General description
Tributylgermanium hydride is a radical generating reagent. Reductive alkylation of active olefins with alkyl halides with tributylgermanium hydride was investigated in detail.
Application
苄基氯化物的有效还原剂。
Packaging
Packaged in glass bottles
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Evaluation of tributylgermanium hydride as a reagent for the reductive alkylation of active olefins with alkyl halides
Pike P, et al.
Tetrahedron, 44(20), 6295-6304 (1988)
Angewandte Chemie (International Edition in English), 31, 1046-1046 (1992)
Tributylgermanium hydride as a replacement for tributyltin hydride in radical reactions.
Bowman WR, et al.
Organic & Biomolecular Chemistry, 2(4), 585-592 (2004)
Theresia Ahrens et al.
Dalton transactions (Cambridge, England : 2003), 45(43), 17495-17507 (2016-11-02)
The reaction of the silyl complex [Rh{Si(OEt)
商品
High Purity Metalorganic Precursors for CPV Device Fabrication
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