419567
异丙烯基溴化镁 溶液
0.5 M in THF
别名:
1-Methylvinylmagnesium bromide, 1-Propen-2-ylmagnesium bromide, 2-Propen-2-ylmagnesium bromide, Bromo prop-1-en-2-yl magnesium, Bromo(isopropenylmagnesium), Isopropenylmagnesium bromide
登录 查看组织和合同定价。
选择尺寸
变更视图
关于此项目
线性分子式:
CH2=C(CH3)MgBr
化学文摘社编号:
分子量:
145.28
PubChem Substance ID:
UNSPSC Code:
12352103
NACRES:
NA.22
EC Index Number:
603-688-6
Beilstein/REAXYS Number:
3587297
MDL number:
Quality Level
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
0.5 M in THF
bp
67 °C
density
0.935 g/mL at 25 °C
SMILES string
CC(=C)[Mg]Br
InChI
1S/C3H5.BrH.Mg/c1-3-2;;/h1H2,2H3;1H;/q;;+1/p-1
InChI key
LFTYALBVGVNGLI-UHFFFAOYSA-M
Application
异丙烯基溴化镁（iPrMgBr）溶液（0.5M，溶剂为THF）已被用于格氏反应，这是制备佐芬普利拉和(S)-(−)-膦酰三磷酸的关键步骤。 在(+)-desepoxyasperdiol的全合成中，它还可以用于光学活性环氧醇的区域选择性开环。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Still not finding the right product?
Explore all of our products under 异丙烯基溴化镁 溶液
signalword
Danger
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
35.6 °F - closed cup
flash_point_c
2 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
法规信息
危险化学品
此项目有
11C-Radiosynthesis and preliminary human evaluation of the disposition of the ACE inhibitor [11C] zofenoprilat.
Matarrese M, et al.
Bioorganic & Medicinal Chemistry, 12(3), 603-611 (2004)
Total synthesis of (+)-desepoxyasperdiol.
Tius M A and Fauq A H
Journal of the American Chemical Society, 108(5), 1035-1039 (1986)
Chemoenzymatic formal synthesis of (S)-(?)-phosphonotrixin.
Chenevert R, et al.
Tetrahedron Asymmetry, 15(12), 1889-1892 (2004)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 419567-100ML | 04061832092362 |
| 419567-800ML | 04061838127488 |