419613
2-甲基-1-丙烯基溴化镁 溶液
0.5 M in THF
别名:
(2-Methylpropenyl)magnesium bromide, 2,2-Dimethylvinylmagnesium bromide, Isobutenylmagnesium bromide
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关于此项目
线性分子式:
(CH3)2C=CHMgBr
化学文摘社编号:
分子量:
159.31
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Quality Segment
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
0.5 M in THF
density
0.952 g/mL at 25 °C
SMILES string
C\C(C)=C\[Mg]Br
InChI
1S/C4H7.BrH.Mg/c1-4(2)3;;/h1H,2-3H3;1H;/q;;+1/p-1
InChI key
BKVIQODYSREJQH-UHFFFAOYSA-M
General description
2-甲基-1-丙烯基溴化镁是一种杂环有机化合物。它被用于化学合成中的格氏试剂。
Application
用于合成 (2S,3S)-3′-氟代异亮氨酸。
用于研究与芳基甲苯磺酸酯的钯催化偶联反应。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
5.0 °F - closed cup
flash_point_c
-15 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
target_organs
Central nervous system, Respiratory system
supp_hazards
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 2