420042
1-甲基-2-丙烯基氯化镁 溶液
0.5 M in THF
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关于此项目
线性分子式:
H2C=CHCH(CH3)MgCl
化学文摘社编号:
分子量:
114.86
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C4H7.ClH.Mg/c1-3-4-2;;/h3-4H,1H2,2H3;1H;/q;;+1/p-1
SMILES string
CC([Mg]Cl)C=C
InChI key
RTJGBPYEBKZQGE-UHFFFAOYSA-M
reaction suitability
reaction type: Grignard Reaction
concentration
0.5 M in THF
bp
67 °C
density
0.917 g/mL at 25 °C
Quality Level
Application
1-Methyl-2-propenylmagnesium chloride is a Grignard type allylating reagent that can be used for the preparation of corresponding homoallylic alcohols by reacting with various aldehydes. It can also be utilized in the synthesis of 3,4-dihydro-4-(1-methyl-2-propen-1-yl)-2(1H)-pyrimidinethione derivatives by treating with 2-mercaptopyrimidine.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
target_organs
Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
-4.0 °F - closed cup
flash_point_c
-20 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Water accelerated allylation of aldehydes by using water tolerant Grignard-type allylating agents from allylmagnesium chloride and various metallic salts
Fukuma T, et al.
Chemistry Letters (Jpn), 31(3), 376-377 (2002)
Addition of Organolithium and Grignard Reagents to Pyrimidine-2 (1 H)-thione: Easy Access to 4-Substituted 3, 4-Dihydropyrimidine-2 (1 H)-thiones
Sosnicki JG
Phosphorus, Sulfur, and Silicon and the Related Elements, 184(8), 1946-1957 (2009)
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