425508
2,6-二甲基苯基溴化镁 溶液
1.0 M in THF
别名:
2,6-Xylylmagnesium bromide, Bromo(2,6-dimethylphenyl)magnesium
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关于此项目
线性分子式:
(CH3)2C6H3MgBr
化学文摘社编号:
分子量:
209.37
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Quality Segment
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
1.0 M in THF
bp
65-67 °C
density
0.998 g/mL at 25 °C
SMILES string
Cc1cccc(C)c1[Mg]Br
InChI
1S/C8H9.BrH.Mg/c1-7-4-3-5-8(2)6-7;;/h3-5H,1-2H3;1H;/q;;+1/p-1
InChI key
BIGUVDUZGAJWQK-UHFFFAOYSA-M
Application
2,6-Dimethylphenylmagnesium bromide can be used:
- As an intermediate in the synthesis of dibutyl(5,10-dihydro-1,9-di-p-toluoyl-5-p-tolyldipyrrinato)tin(IV), which is further used in the preparation of zinc-based porphyrin.
- As a substrate in the preparation of substituted fluorenes by reacting with 2-substituted arenesulfonates and dihaloarenes.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
-2.2 °F - closed cup
flash_point_c
-19 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
target_organs
Central nervous system, Respiratory system
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 2