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Merck
CN

429007

1-丙炔溴化镁 溶液

0.5 M in THF

别名:

1-Propyn-1-ylmagnesium bromide, Bromo(prop-1-yn-1-yl)magnesium, Bromo-1-propynylmagnesium

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关于此项目

线性分子式:
CH3C≡CMgBr
化学文摘社编号:
分子量:
143.26
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3929146
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Quality Level

reaction suitability

reaction type: Grignard Reaction

packaging

Sure/Seal of

concentration

0.5 M in THF

bp

65-67 °C

density

0.941 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC#C[Mg]Br

InChI

1S/C3H3.BrH.Mg/c1-3-2;;/h1H3;1H;/q;;+1/p-1

InChI key

YVJBCTFVENNIOV-UHFFFAOYSA-M

General description

-丙基溴化镁溶液系0.5M四氢呋喃中的1-丙基溴化镁。该溶液在化学合成中作为格氏试剂使用。该研究试剂可用于化学和有机转化。它可用作一种试剂,以通过Mitsunobu反应将[11C]CO2转化为[11C]酰胺。

Application

制备羟基烯炔,该羟基烯炔经金(I)-催化的苯环化反应可生成四氢化萘。

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC


signalword

Danger

target_organs

Central nervous system, Respiratory system

supp_hazards

存储类别

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

30.2 °F - closed cup

flash_point_c

-1 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 2

法规信息

危险化学品

此项目有



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The [3+ 2] cycloaddition route to 5-carbomethoxy-4h-1, 2, 3-triazolo [1, 5-a][1] benzazepines from baylis-hillman acetates of 2-azidobenzaldehydes
Song YS and Lee KJ
Journal of Heterocyclic Chemistry, 43(6), 1721-1724 (2006)
Christiane M Grisé et al.
Organic letters, 8(25), 5905-5908 (2006-12-01)
We report a gold-catalyzed benzannulation of 3-hydroxy-1,5-enynes to generate tetrahydronaphthalenes. This mild process proves to be an effective method to synthesize various metasubstituted aromatic rings in good yields. [reaction: see text]
From [11 C] CO 2 to [11 C] amides: a rapid one-pot synthesis via the Mitsunobu reaction
Bongarzone S, et al.
Chemical Communications (Cambridge, England), 53(38), 5334-5337 (2017)



全球贸易项目编号

货号GTIN
429007-800ML04061838135629
429007-100ML04061832105192