429007
1-丙炔溴化镁 溶液
0.5 M in THF
别名:
1-Propyn-1-ylmagnesium bromide, Bromo(prop-1-yn-1-yl)magnesium, Bromo-1-propynylmagnesium
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关于此项目
线性分子式:
CH3C≡CMgBr
化学文摘社编号:
分子量:
143.26
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3929146
Quality Segment
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
0.5 M in THF
bp
65-67 °C
density
0.941 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
CC#C[Mg]Br
InChI
1S/C3H3.BrH.Mg/c1-3-2;;/h1H3;1H;/q;;+1/p-1
InChI key
YVJBCTFVENNIOV-UHFFFAOYSA-M
General description
-丙基溴化镁溶液系0.5M四氢呋喃中的1-丙基溴化镁。该溶液在化学合成中作为格氏试剂使用。该研究试剂可用于化学和有机转化。它可用作一种试剂，以通过Mitsunobu反应将[11C]CO2转化为[11C]酰胺。
Application
制备羟基烯炔，该羟基烯炔经金(I)-催化的苯环化反应可生成四氢化萘。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
30.2 °F - closed cup
flash_point_c
-1 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 2