429147
二羰基乙酰丙酮铱(I)
别名:
Dicarbonyl(2,4-pentanedionato)iridium
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关于此项目
线性分子式:
Ir(acac)(CO2)
化学文摘社编号:
分子量:
347.35
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
InChI
1S/C5H8O2.2CO.Ir/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;
SMILES string
[C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Ir]
InChI key
DFIAYCFHPDOZLK-FGSKAQBVSA-M
reaction suitability
core: iridium, reagent type: catalyst
Quality Level
Application
Catalyst for isomerization and anti-Markovnikov arylation of olefins
Reactant for:
Reactant for:
- Oxidative addition of perfluoroalkyl iodides
- Synthesis of iridium heterocycles
- Scaffolding of iridium complexes
- Metal carbonyl cluster synthesis
- Mixed-bridged bimetallic d8 complex synthesis
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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