442178
对甲苯基溴化镁 溶液
1.0 M in THF
别名:
4-甲基苯基溴化镁
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关于此项目
线性分子式:
CH3C6H4MgBr
化学文摘社编号:
分子量:
195.34
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
636491
产品名称
对甲苯基溴化镁 溶液, 1.0 M in THF
InChI
1S/C7H7.BrH.Mg/c1-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1
SMILES string
Cc1ccc([Mg]Br)cc1
InChI key
ZRJNGFJIBZKXTP-UHFFFAOYSA-M
reaction suitability
reaction type: Grignard Reaction
concentration
1.0 M in THF
bp
65-67 °C
density
1.002 g/mL at 25 °C
Quality Level
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Application
对甲苯基溴化镁是一种常用的格氏试剂。它也可以用于多种交叉偶联反应中。
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F
flash_point_c
-17 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Palladium-and Nickel-Catalyzed Kumada Cross-Coupling Reactions of gem-Difluoroalkenes and Monofluoroalkenes with Grignard Reagents.
Dai W
The Journal of Organic Chemistry, 79(21), 10537-10546 (2014)
Dinuclear Iron Complex-Catalyzed Cross-Coupling of Primary Alkyl Fluorides with Aryl Grignard Reagents.
Mo Z, et al.
Organometallics, 31(18), 6518-6521 (2012)
Palladium-catalyzed cross coupling of Grignard reagents with in situ-derived enol phosphates.
Miller JA
Tetrahedron Letters, 43(39), 7111-7114 (2002)
Takuji Hatakeyama et al.
Journal of the American Chemical Society, 131(33), 11949-11963 (2009-07-31)
Combinations of N-heterocyclic carbenes (NHCs) and fluoride salts of the iron-group metals (Fe, Co, and Ni) have been shown to be excellent catalysts for the cross-coupling reactions of aryl Grignard reagents (Ar(1)MgBr) with aryl and heteroaryl halides (Ar(2)X) to give
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