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47623

Fmoc-Tyr(tBu)-OH

Name: Fmoc-Tyr(<I>t</I>Bu)-OH
Brand: ALDRICH

≥98.0% (HPLC), for peptide synthesis

别名:

N-(9-芴甲氧羰基)-O-叔丁基-L-酪氨酸, Fmoc-O-叔丁基-L-酪氨酸

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关于此项目

经验公式（希尔记法）:

C₂₈H₂₉NO₅

化学文摘社编号:

71989-38-3

分子量:

459.53

NACRES:

NA.26

PubChem Substance ID:

57651043

eCl@ss:

32160406

UNSPSC Code:

12352209

EC Number:

276-262-7

MDL number:

MFCD00037129

Beilstein/REAXYS Number:

4216652

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属性

产品名称

Fmoc-Tyr(tBu)-OH, ≥98.0% (HPLC)

Quality Level

100

assay

≥98.0% (HPLC)

form

powder

optical activity

[α]20/D −29±2°, c = 1% in DMF

reaction suitability

reaction type: Fmoc solid-phase peptide synthesis

mp

153-156 °C (lit.)

application(s)

peptide synthesis

functional group

Fmoc

storage temp.

2-8°C

SMILES string

CC(C)(C)Oc1ccc(C[C@H](NC(=O)OCC2c3ccccc3-c4ccccc24)C(O)=O)cc1

InChI

1S/C28H29NO5/c1-28(2,3)34-19-14-12-18(13-15-19)16-25(26(30)31)29-27(32)33-17-24-22-10-6-4-8-20(22)21-9-5-7-11-23(21)24/h4-15,24-25H,16-17H2,1-3H3,(H,29,32)(H,30,31)/t25-/m0/s1

InChI key

JAUKCFULLJFBFN-VWLOTQADSA-N

说明

General description

Fmoc-Tyr(tBu)-OH也称为Fmoc-O-叔丁基-L-酪氨酸，通常用于Fmoc固相法肽合成。

Application

Fmoc-Tyr(tBu)-OH可用于通过水中固相反应合成亮氨酸-脑啡肽酰胺(Leu-Enkephalin Amide)。也用于合成氨基酸衍生物，例如Fmoc-Tyr-OAllyl。

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存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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European Journal of Organic Chemistry, 2015, 7043-7052 (2015)

Solid-phase peptide synthesis using nanoparticulate amino acids in water

K Hojo

Journal of Peptide Science, 13, 493-497 (2007)

A New Caged-Glutamine Derivative as a Tool To Control the Assembly of Glutamine-Containing Amyloidogenic Peptides.

Loay Awad et al.

Chembiochem : a European journal of chemical biology, 17(24), 2353-2360 (2016-10-28)

We present the design, synthesis, and characterization of a novel photocaged glutamine derivative (modified on the side chain of glutamine), and describe its use in enhancing peptide stability and solubility. Our results demonstrate that this approach can be used to

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全球贸易项目编号

货号	GTIN
47623-10G-F	04061832362199
47623-1KG-F	04061826222683
47623-100G-F	04061832362182
47623-25G-F	04061832362205