482358
四氟硼酸二铁
technical grade
别名:
双（环戊二烯基）四氟硼酸铁, 四氟硼酸二环戊二烯基铁, 氟硼酸二环戊二烯基铁
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关于此项目
经验公式（希尔记法）:
C10H10BF4Fe
化学文摘社编号:
分子量:
272.84
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
InChI
1S/2C5H5.BF4.Fe/c2*1-2-4-5-3-1;2-1(3,4)5;/h2*1-5H;;/q;;-1;+1
SMILES string
[Fe+].F[B-](F)(F)F.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI key
ZSPXIHLQPWVOQR-UHFFFAOYSA-N
grade
technical grade
reaction suitability
core: iron, reagent type: catalyst
mp
178 °C (dec.) (lit.)
Quality Level
General description
四氟硼酸二茂铁[FeCp2][BF4]是化学合成中常用的二茂铁盐之一。二茂铁盐通常用作路易斯酸催化剂、单电子氧化剂和电子供体。
Application
四氟硼酸二茂铁可用作：
- 合成单阳离子Co(II)配合物[CpCo(azpy)]+的氧化剂
- 环氧化物开环和活化羰基进行加成或环加成反应中的路易斯酸催化剂
- 与Cl-源一起使用时的氧化剂
- 锡唑二价阴离子与双锡唑-1,2-二价阴离子之间的可逆氧化还原试剂
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Formation of exceptionally weak C?C bonds by metal-templated pinacol coupling
Folkertsma E., et al.
Dalton Transactions, 46, 6177?6182-6177?6182 (2017)
Protonation of a cobalt phenylazopyridine complex at the ligand yields a proton, hydride, and hydrogen atom transfer reagent
McLoughlin EA, et al.
Journal of the American Chemical Society, 140(41), 13233-13241 (2018)
Fe (Cp) 2BF4: An efficient Lewis acid catalyst for the aminolysis of epoxides
Yadav GD, et al.
thieme, 629-634 (2014)
Mutlu Sönmez Celebi et al.
Talanta, 78(2), 405-409 (2009-02-11)
A new surface based on poly(vinylferrocenium) (PVF(+))-modified platinum electrode was developed for determination of Hg(2+) ions in aqueous solutions. The polymer was electrodeposited on platinum electrode by constant potential electrolysis as PVF(+)ClO(4)(-). Cl(-) ions were then attached to the polymer
Leigh Aldous et al.
Physical chemistry chemical physics : PCCP, 19(35), 24255-24263 (2017-08-30)
Entropic changes inherent within a redox process typically result in significant temperature sensitivity. This can be utilised positively or can be a detrimental process. This study has investigated the thermoelectrochemical properties (temperature-dependant electrochemistry) of the ferrocenium|ferrocene redox couple in an
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