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Merck
CN

499552

锌 制备

5 g/dL Zn2+ in THF, highly reactive Rieke®metal

别名:

Zn

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关于此项目

线性分子式:
Zn
化学文摘社编号:
分子量:
65.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
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Quality Level

reaction suitability

core: zinc, reagent type: catalyst

concentration

5 g/dL Zn2+ in THF

density

0.949 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

[Zn]

InChI

1S/Zn

InChI key

HCHKCACWOHOZIP-UHFFFAOYSA-N

Application

Rieke®锌可用于还原常见有机官能团,如芳硝基化合物、共轭醛、芳炔和苯丙炔酸酯。

Legal Information

Rieke Metals, Inc.公司产品。
Rieke 是Rieke Metals, Inc.公司的注册商标。
Rieke is a registered trademark of Rieke Metals, Inc.


signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

1.0 °F - closed cup

flash_point_c

-17.22 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

监管及禁止进口产品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

Metal-enhanced organic synthesis via organometallic intermediates is a widely used preparative route for thousands of organic compounds.


Rieke zinc as a reducing agent for common organic functional groups
Kroemer J, et al.
Tetrahedron Letters, 47(36), 6339-6341 (2006)
Casper Groth et al.
Development (Cambridge, England), 140(14), 3018-3027 (2013-06-21)
Developmental patterning requires the precise interplay of numerous intercellular signaling pathways to ensure that cells are properly specified during tissue formation and organogenesis. The spatiotemporal function of the Notch signaling pathway is strongly influenced by the biosynthesis and intracellular trafficking
I A Popov et al.
Molekuliarnaia biologiia, 47(3), 498-504 (2013-07-31)
Alzheimer's disease, is a lethal neurodegenerative pathology, characterized by the formation of soluble neurotoxic oligomers of the human amyloid-beta peptide Abeta which get accumulated forming polymeric extracellular aggregates (so-called amyloid plaques). The isomerized at aspartate 7 isoform of the human



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货号GTIN
499552-100ML04061832422039