499552
锌 制备
5 g/dL Zn2+ in THF, highly reactive Rieke®metal
别名:
Zn
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关于此项目
线性分子式:
Zn
化学文摘社编号:
分子量:
65.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
InChI
1S/Zn
SMILES string
[Zn]
InChI key
HCHKCACWOHOZIP-UHFFFAOYSA-N
reaction suitability
core: zinc, reagent type: catalyst
density
0.949 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
concentration
5 g/dL Zn2+ in THF
Application
Rieke®锌可用于还原常见有机官能团，如芳硝基化合物、共轭醛、芳炔和苯丙炔酸酯。
Legal Information
Rieke Metals, Inc.公司产品。
Rieke 是Rieke Metals, Inc.公司的注册商标。
Rieke 是Rieke Metals, Inc.公司的注册商标。
Rieke is a registered trademark of Rieke Metals, Inc.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
1.0 °F - closed cup
flash_point_c
-17.22 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Rieke zinc as a reducing agent for common organic functional groups
Kroemer J, et al.
Tetrahedron Letters, 47(36), 6339-6341 (2006)
Casper Groth et al.
Development (Cambridge, England), 140(14), 3018-3027 (2013-06-21)
Developmental patterning requires the precise interplay of numerous intercellular signaling pathways to ensure that cells are properly specified during tissue formation and organogenesis. The spatiotemporal function of the Notch signaling pathway is strongly influenced by the biosynthesis and intracellular trafficking
I A Popov et al.
Molekuliarnaia biologiia, 47(3), 498-504 (2013-07-31)
Alzheimer's disease, is a lethal neurodegenerative pathology, characterized by the formation of soluble neurotoxic oligomers of the human amyloid-beta peptide Abeta which get accumulated forming polymeric extracellular aggregates (so-called amyloid plaques). The isomerized at aspartate 7 isoform of the human
Cigdem Karakukcu et al.
Clinical laboratory, 59(5-6), 557-562 (2013-07-20)
The aim of this study was to assess the acute and chronic effects of vigorous physical activity, with and without zinc supplementation, on distribution of elements in young amateur boxers. The 8 week intervention trial experiment was designed with 32
M E Kuyumcu et al.
European review for medical and pharmacological sciences, 17(11), 1467-1471 (2013-06-19)
Zinc is one of the most important elements for human body. Zinc deficiency can occur in any age, if it is seen in elderly its clinical results can be more harmful due to already diminished functions. Some studies showed zinc
商品
Metal-enhanced organic synthesis via organometallic intermediates is a widely used preparative route for thousands of organic compounds.
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