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Merck
CN

510068

Raney®-镍

W.R. Grace and Co. Raney® 3202, slurry, in H2O, active catalyst

别名:

海绵镍

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关于此项目

线性分子式:
AlNi
化学文摘社编号:
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
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InChI

1S/Al.Ni

SMILES string

[Al].[Ni]

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

form

slurry

reaction suitability

core: nickel, reagent type: catalyst

manufacturer/tradename

W.R. Grace and Co. Raney® 3202

concentration

in H2O

Quality Level

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Application

Useful as a selective reducing agent for hydrogenation of organic compounds

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.

signalword

Danger

Hazard Classifications

Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1

存储类别

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Nitrile reduction in the presence of Boc-protected amino groups by catalytic hydrogenation over palladium-activated Raney-nickel.
B Klenke et al.
The Journal of organic chemistry, 66(7), 2480-2483 (2001-04-03)
Tsukinoki, T.; Kanda, T.
Tetrahedron Letters, 41, 5865-5865 (2000)
Toth, M.; Somsak, L.,
Tetrahedron Letters, 42, 2723-2723 (2001)
Barrero, A. F.; Alvarez-Manzaneda, E. J. et al.
Synthesis, 197-197 (2000)
S M Marchan et al.
The European journal of prosthodontics and restorative dentistry, 21(1), 24-28 (2013-05-21)
Posterior resin bonded cast metal restorations (adhesive onlays) were used in a variety of clinical scenarios including: management of tooth wear and cracked tooth, as retainers for fixed bridge work, for correction of the occlusal plane and in providing cuspal

商品

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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