510068
Raney®-镍
W.R. Grace and Co. Raney® 3202, slurry, in H2O, active catalyst
别名:
海绵镍
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关于此项目
线性分子式:
AlNi
化学文摘社编号:
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
InChI
1S/Al.Ni
SMILES string
[Al].[Ni]
InChI key
NPXOKRUENSOPAO-UHFFFAOYSA-N
form
slurry
reaction suitability
core: nickel, reagent type: catalyst
manufacturer/tradename
W.R. Grace and Co. Raney® 3202
concentration
in H2O
Quality Level
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Application
Useful as a selective reducing agent for hydrogenation of organic compounds
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
新产品
此项目有
Barrero, A. F.; Alvarez-Manzaneda, E. J. et al.
Synthesis, 197-197 (2000)
Nitrile reduction in the presence of Boc-protected amino groups by catalytic hydrogenation over palladium-activated Raney-nickel.
B Klenke et al.
The Journal of organic chemistry, 66(7), 2480-2483 (2001-04-03)
Tsukinoki, T.; Kanda, T.
Tetrahedron Letters, 41, 5865-5865 (2000)
Toth, M.; Somsak, L.,
Tetrahedron Letters, 42, 2723-2723 (2001)
A J Feilzer et al.
Nederlands tijdschrift voor tandheelkunde, 120(6), 335-341 (2013-07-19)
Orally applied metal alloys can cause undesirable physical effects. A distinction needs to be made in this respect between local and systemic reactions and toxic and immunological reactions. A case is presented which illustrates this problem. In this case, the
商品
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
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