526797
环丙基溴化镁 溶液
0.5 M in THF
别名:
Bromocyclopropylmagnesium
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关于此项目
线性分子式:
C3H5MgBr
化学文摘社编号:
分子量:
145.28
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
reaction suitability
reaction type: Grignard Reaction
Quality Segment
packaging
Sure/Seal™ of
concentration
0.5 M in THF
bp
65 °C
density
0.968 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
Br[Mg]C1CC1
InChI
1S/C3H5.BrH.Mg/c1-2-3-1;;/h1H,2-3H2;1H;/q;;+1/p-1
InChI key
QUPLLJGAJVXXBW-UHFFFAOYSA-M
Application
环丙基溴化镁溶液已被用于可应用作为制备氨基丙基茚关键步骤的Grignard反应中，而氨基丙基茚则是Grundmann酮的一种化学型氧化角鲨烯环化酶（OSC）抑制剂。它可与硼酸三甲酯反应以形成环丙基硼酸，其可通过与不同的芳基和杂芳基溴化物发生铃木型偶联反应以形成环丙基加合物。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
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Danger
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
1.0 °F - closed cup
flash_point_c
-17.22 °C - closed cup
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 2