529680
氯化亚锰 水合物
99.999% trace metals basis
别名:
Manganese chloride hydrate
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关于此项目
线性分子式:
MnCl2 · xH2O
化学文摘社编号:
分子量:
125.84 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
231-869-6
MDL number:
InChI key
BXRRQHBNBXJZBQ-UHFFFAOYSA-L
InChI
1S/2ClH.Mn.H2O/h2*1H;;1H2/q;;+2;/p-2
SMILES string
O.Cl[Mn]Cl
assay
99.999% trace metals basis
reaction suitability
core: manganese, reagent type: catalyst
mp
122 °C (lit.)
density
1.913 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
Application
Starting material for preparation of organomanganese chloride reagents; Catalyst for reductionof vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- and stereo-selectively.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - STOT RE 2
target_organs
Brain
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Cahiez, G.; Laboue, B.
Tetrahedron Letters, 33, 4439-4439 (1992)
Fujii, H.; Oshima, K.; Utimoto, K.
Tetrahedron Letters, 32, 6147-6147 (1991)
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