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Merck
CN

560030

Sigma-Aldrich

叔丁醇锆

electronic grade, 99.999% trace metals basis

别名:

ZTB, 叔丁醇锆, 四叔丁氧基锆, 四叔丁氧化锆

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关于此项目

线性分子式:
Zr[OC(CH3)3]4
化学文摘社编号:
2081-12-1
分子量:
383.68
Beilstein:
3681870
MDL编号:
MFCD00075085
UNSPSC代码:
12352103
PubChem化学物质编号:
24879839
NACRES:
NA.23

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等级

electronic grade

质量水平

100

方案

99.999% trace metals basis

表单

liquid

反应适用性

core: zirconium
reagent type: catalyst

折射率

n20/D 1.424 (lit.)

沸点

81 °C/3 mmHg (lit.)

密度

0.985 g/mL at 25 °C (lit.)

SMILES字符串

CC(C)(C)O[Zr](OC(C)(C)C)(OC(C)(C)C)OC(C)(C)C

InChI

1S/4C4H9O.Zr/c4*1-4(2,3)5;/h4*1-3H3;/q4*-1;+4

InChI key

BGGIUGXMWNKMCP-UHFFFAOYSA-N

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相关类别

一般描述

Zirconium(IV) tert-butoxide, electronic grade (99.999% trace metals basis), is a high-purity, moisture-sensitive organometallic compound widely used as a catalyst and as a precursor for solution and vapor deposition processes, especially in the fabrication of energy materials and advanced ceramics. Its exceptional purity makes it ideal for applications in microelectronics, catalysis, and the synthesis of high-performance inorganic materials.

应用

叔丁醇锆(IV)可用于合成手性N-叔丁烷亚磺酰基三氟甲基酮亚胺。用于光学应用不锈钢基材上的氧化锆涂层可以通过叔丁醇锆(IV)前体，通过溶胶凝胶法进行制备。

特点和优势

  • High Purity and Low Total Metallic Impurities: Suitable for sensitive applications due to low impurity content and absence of residual chloride
  • Moisture Sensitivity: Highly sensitive to moisture; must be handled under inert atmosphere
  • Reactivity: Readily hydrolyzes to form zirconia (ZrO₂) or mixed oxides

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

183.2 °F - closed cup

闪点(°C)

84 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBN3021
SHBM5524
SHBD4702V
SHBD4699V
SHBC5545V

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Efficient preparation of Ellman?s imines from trifluoromethyl ketones promoted by zirconium(IV) tert-butoxide
Kawanami T, et al.
Tetrahedron Letters, 54(52), 7202-7205 (2013)
Fabrication of zirconium oxide coatings on stainless steel by a combined laser/sol?gel technique.
Adraider Y, et al.
Ceramics International, 39(8), 9665-9670 (2013)

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