561657
（1,3-二恶烷-2-基乙基）溴化镁 溶液
0.5 M in THF
别名:
1,3-Dioxane - 2-ethyl- magnesium complex, [2-(1,3-Dioxan-2-yl)ethyl]magnesium bromide
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关于此项目
经验公式（希尔记法）:
C6H11BrMgO2
化学文摘社编号:
分子量:
219.36
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
reaction suitability
reaction type: Grignard Reaction
Quality Segment
packaging
Sure/Seal™ of
concentration
0.5 M in THF
bp
65 °C
density
0.951 g/mL at 25 °C
functional group
ether
storage temp.
2-8°C
SMILES string
Br[Mg]CCC1OCCCO1
InChI
1S/C6H11O2.BrH.Mg/c1-2-6-7-4-3-5-8-6;;/h6H,1-5H2;1H;/q;;+1/p-1
InChI key
JYNXRXBIEHSSLR-UHFFFAOYSA-M
Application
(1,3-Dioxan-2-ylethyl)magnesium bromide can be used:
- In a Grignard addition-acylation method for the preparation of enamides.
- To prepare trisubstituted allenes by reacting with propargylic ammonium salts.
- In one of the key synthetic steps for the synthesis of febrifugine based antimalarial drugs.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标
supp_hazards
存储类别
3 - Flammable liquids
flash_point_f
No data available
flash_point_c
No data available
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system