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About This Item
经验公式（希尔记法）:
C14H9BrMg
CAS Number:
分子量:
281.43
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
反应适用性
reaction type: Grignard Reaction
质量水平
浓度
0.5 M in THF
沸点
65 °C (lit.)
密度
0.970 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
Br[Mg]c1cc2ccccc2c3ccccc13
InChI
1S/C14H9.BrH.Mg/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13;;/h1-9H;1H;/q;;+1/p-1
InChI key
ACMUZKQPXSHTGB-UHFFFAOYSA-M
一般描述
9-phenanthrylmagnesium bromide is a Grignard reagent. It can be prepared using magnesium turnings and 9-bromophenanthrene under anhydrous condition.
应用
9-Phenanthrylmagnesium bromide can be used as a reagent to prepare:
- 9-alkyl and 9-arylthiophenanthrenes by reacting with alkyl or aryl thiol compounds.
- (S)-α-methylbenzyl 1-(9-phenanthryl)-2-naphthoate by treating with (S)- α -methylbenzyl methoxy-2-naphthoate.
- 1-(9-Phenanthryl)-1-phenylethanol (carbinol) by reacting with acetophenone. The obtained carbinol undergoes dehydration reaction in the presence of acetic acid and sulfuric acid to afford 1-(9-phenanthryl)-1-phenylethene (PPE).
法律信息
Rieke ® Metals, Inc. 的产品，®Rieke Metals, Inc. 的注册商标
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
靶器官
Respiratory system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
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