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经验公式(希尔记法):
C5H3BrFN
化学文摘社编号:
分子量:
175.99
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
97%
产品名称
2-溴-5-氟吡啶, 97%
InChI
1S/C5H3BrFN/c6-5-2-1-4(7)3-8-5/h1-3H
SMILES string
Fc1ccc(Br)nc1
InChI key
UODINHBLNPPDPD-UHFFFAOYSA-N
assay
97%
bp
80-83 °C/44 mmHg (lit.)
mp
30-31 °C (lit.)
functional group
bromo
fluoro
Quality Level
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Application
用作酯的钯催化 α-芳基化反应的原料,反应生成 4-吡啶基羧基哌啶。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
163.4 °F - closed cup
flash_point_c
73 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Tetrahedron Letters, 48, 1191-1191 (2007)
"A fast and oxygen-promoted protocol for the ligand-free Suzuki reaction of 2-halogenated pyridines in aqueous media"
Liu C and Yang W
Chemical Communications (Cambridge, England), 41, 6267-6269 (2009)
Lee K and Lee HP
Tetrahedron Letters, 49(27), 4302-4305 (2008)
"A General and Highly Efficient Method for the Construction of Aryl-Substituted N-Heteroarenes"
Liu C, et al.
European Journal of Organic Chemistry, 1010(29), 5548-5551 (2010)
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