651664
叠氮化四丁基铵
别名:
N,N,N-三丁基-1-丁氨基叠氮化物, 四丁基氮化铵
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关于此项目
经验公式（希尔记法）:
C16H36N4
化学文摘社编号:
分子量:
284.48
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352116
MDL number:
Form:
solid
InChI
1S/C16H36N.N3/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-3-2/h5-16H2,1-4H3;/q+1;-1
SMILES string
[N-]=[N+]=[N-].CCCC[N+](CCCC)(CCCC)CCCC
InChI key
GMRIOAVKKGNMMV-UHFFFAOYSA-N
form
solid
reaction suitability
reaction type: click chemistry
mp
84-88 °C (lit.)
functional group
amine, azide
storage temp.
2-8°C
Quality Level
Application
四丁基叠氮化铵可用作以下合成反应的试剂：
它还用作环状碳酸酯形成的催化剂。
- 杂芳基环双环吗啉
- 基于氰基亚胺的组织蛋白酶 C 抑制剂
- 三亚甲基碳酸酯
- 初级叠氮化物对腈的好氧氧化转化
- 四配位硼的取代反应
它还用作环状碳酸酯形成的催化剂。
用于合成以下化合物的试剂：
用于以下反应的试剂：
用于形成碳酸盐的催化剂
- 杂芳基化的双环吗啉
- 基于氰基亚胺的组织蛋白酶 C 抑制剂
- 三亚甲基碳酸酯
用于以下反应的试剂：
- 初级叠氮化物向腈的好氧氧化转化
- 四配位硼的取代反应
用于形成碳酸盐的催化剂
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
法规信息
监管及禁止进口产品
此项目有
Synthesis of bicyclic sugar azido acids and their incorporation in cyclic peptides.
Peri F, et al.
Chemical Communications (Cambridge, England), 2303-2304 (2000)
Aerobic oxidative transformation of primary azides to nitriles by ruthenium hydroxide catalyst.
He J, et al.
The Journal of Organic Chemistry, 76(11), 4606-4610 (2011)
Substitution Reactions at Tetracoordinate Boron: Synthesis of N-Heterocyclic Carbene Boranes with Boron- Heteroatom Bonds.
Solovyev A, et al.
Journal of the American Chemical Society, 132(42), 15072-15080 (2010)
A facile catalytic synthesis of trimethylene carbonate from trimethylene oxide and carbon dioxide.
Darensbourg DJ, et al.
Green Chemistry, 12(8), 1376-1379 (2010)
Mark Furber et al.
Journal of medicinal chemistry, 57(6), 2357-2367 (2014-03-07)
A lead generation and optimization program delivered the highly selective and potent CatC inhibitor 10 as an in vivo tool compound and potential development candidate. Structural studies were undertaken to generate SAR understanding.
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