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Merck
CN

651745

氯化亚铜

AnhydroBeads, ≥99.99% trace metals basis

别名:

一氯化铜

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关于此项目

线性分子式:
CuCl
化学文摘社编号:
分子量:
99.00
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-842-9
MDL number:
Assay:
≥99.99% trace metals basis
Grade:
synthesis grade
Solubility:
slightly soluble 0.47 g/L at 20 °C
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产品名称

氯化亚铜, AnhydroBeads, ≥99.99% trace metals basis

InChI

1S/ClH.Cu/h1H;/q;+1/p-1

InChI key

OXBLHERUFWYNTN-UHFFFAOYSA-M

SMILES string

Cl[Cu]

grade

synthesis grade

vapor pressure

1.3 mmHg ( 546 °C)

product line

AnhydroBeads

assay

≥99.99% trace metals basis

reaction suitability

core: copper
reagent type: catalyst

impurities

≤100.0 ppm Trace Metal Analysis

bp

1490 °C (lit.)

mp

430 °C (lit.)

solubility

slightly soluble 0.47 g/L at 20 °C

application(s)

electroplating
material synthesis precursor

Quality Level

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Application

CuCl 可作为引发剂用于 α,β-不饱和酮的湿法锡化及其它类似自由基反应。
作为自由基反应(如 α,β-不饱和酮的锡氢化作用)的引发剂表现出独特的性质。

General description

铜 (I) 氯化物的结构在室温下与闪锌矿晶体相似,在 407°C 时结构为纤锌矿,在更高的温度下形成铜 (I) 氯化物蒸气(通过质谱测定)。

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


历史批次信息供参考:

分析证书(COA)

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Mimi Liu et al.
PloS one, 15(5), e0232184-e0232184 (2020-05-06)
The ternary chalcogenide Cu3VSe4 (CVSe) with sulvanite structure has been theoretically predicted to be a promising candidate for photovoltaic applications due to its suitable bandgap for solar absorption and the relatively earth-abundant elements in its composition. To realize the absorber
Madelung O
Semiconductors: Data Handbook null
Chethana Gadiyar et al.
Chemical science, 9(25), 5658-5665 (2018-08-01)
Nanocrystal-seeded synthesis relies on the reaction of nanocrystal seeds with a molecular precursor and it can be regarded as the link between sol-gel and solid-state chemistries. This synthesis approach aims at accessing compositionally complex materials, yet to date its full
Yi-Fan Zhao et al.
Journal of colloid and interface science, 448, 380-388 (2015-03-11)
Here we describe the development of versatile antifouling polyethersulfone (PES) filtration membranes modified via surface grafting of zwitterionic polymers from a reactive amphiphilic copolymer additive. Amphiphilic polyethersulfone-block-poly(2-hydroxyethyl methacrylate) (PES-b-PHEMA) was beforehand designed and used as the blending additive of PES
Xiaoliang Xu et al.
Organic letters, 12(5), 897-899 (2010-02-04)
Promoted by CuCl/CCl(4), a variety of sulfonyl azides and tertiary amines were successfully coupled to give sulfonyl amidine derivatives in good to excellent yields. A possible mechanism for this reaction is discussed.

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