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Merck
CN

653667

Pd(0) EnCat® 30NP

wet, nanoparticles, extent of labeling: 0.4 mmol/g Pd(0) loading (dry basis)

别名:

聚脲基质微囊化钯(0)

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关于此项目

经验公式（希尔记法）:
Pd
分子量:
106.42
UNSPSC Code:
12161600
NACRES:
NA.22
MDL number:
MFCD06798789

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产品名称

Pd(0) EnCat® 30NP, wet, nanoparticles, extent of labeling: 0.4 mmol/g Pd(0) loading (dry basis)

form

wet
nanoparticles

contains

0.35-0.43 mmol/g pallladium(0) (dry basis)
45% water

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

extent of labeling

0.4 mmol/g Pd(0) loading (dry basis)

weight

Unit weight includes weight of water.

Quality Level

100

相关类别

Legal Information

Pd EnCat 技术已申请国际专利，包括 PCT/GB 02/03135
EnCat is a registered trademark of Reaxa Ltd.

Other Notes

囊化的钯催化剂，可催化芳基酮和苄醚类化合物的还原。
基质含量 30%

General description

Pd(0) EnCat® 30NP may be used as a catalyst for the selective reduction of aromatic aldehydes, ketones and epoxides to form the corresponding alcohols via hydrogenation.

pictograms

Flame
GHS02

signalword

Danger

hcodes

H251

Hazard Classifications

Self-heat. 1

存储类别

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
00428TH
11821CE
07716HD
07616HD
06907CD

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Steven V Ley et al.
Organic letters, 5(24), 4665-4668 (2003-11-25)
[reaction: see text] Pd nanoparticles (approximately 2 nm in size) microencapsulated in polyurea is an efficient and recyclable catalyst for reductive ring-opening hydrogenolysis of epoxides, using either HCOOH/Et(3)N or H(2) as a hydrogen donor.

相关内容

Pd EnCat™ Encapsulated Palladium Catalysts

Homogeneous palladium catalysts are widely utilized due to their versatility, reactivity and functional group tolerance.

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