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665142

三(三苯基膦金)氧鎓四氟硼酸

solid

别名:

Oxotris((triphenylphosphine)gold) tetrafluoroborate, Oxotris(triphenylphosphine)trigold tetrafluoroborate, Tris[(triphenylphosphino)aurio(I)]oxonium tetrafluoroborate

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关于此项目

经验公式（希尔记法）:
C54H45P3OAu3BF4
化学文摘社编号:
53317-87-6
分子量:
1480.56
UNSPSC Code:
12161600
PubChem Substance ID:
24884716
NACRES:
NA.22
MDL number:
MFCD06658141
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产品名称

三(三苯基膦金)氧鎓四氟硼酸,

form

solid

Quality Level

100

reaction suitability

core: gold, reagent type: catalyst

SMILES string

[Au][O+]([Au])[Au].F[B-](F)(F)F.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

InChI

1S/3C18H15P.3Au.BF4.O/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;2-1(3,4)5;/h3*1-15H;;;;;/q;;;;;;-1;+1

InChI key

HTZIGJMQHZNAQD-UHFFFAOYSA-N

Application

Gold Catalysts — 21st Century ′Gold Rush′
Used in a variety of gold catalyzed reactions including propargyl Claisen rearrangements.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCT4870
MKCQ8574
MKCM3119
MKCL9671
MKCB1979V

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商品

Gold Catalyst Applications

Access gold precatalysts, silver salts, and unsaturated building blocks to accelerate research success in catalysis applications.

Benjamin D Sherry et al.
Journal of the American Chemical Society, 126(49), 15978-15979 (2004-12-09)
Homoallenic alcohols are prepared from propargyl vinyl ethers using a trinuclear gold(I)-oxo complex, [(Ph3PAu)3O]BF4, as a catalyst for propargyl Claisen rearrangement at room temperature. The gold(I)-catalyzed reaction is effective for a diverse collection of propargyl vinyl ethers, including substrates containing

全球贸易项目编号

货号GTIN
665142-250MG04061833281826
665142-1G04061826706626