主要文件

查看所有文档

666564

N -XantPhos

Name: <I>N </I>-XantPhos
Brand: ALDRICH

97%

更环保的选择

别名:

安痛定, 4,6-双(二苯基膦)-10H-吩噁嗪, 4,6-双(二苯基膦)吩噁嗪

登录并加购，请在购物车里查看协议价、货期和发货地。

选择规格

变更视图

关于此项目

线性分子式:

(C₆H₃)₂NHO(P(C₆H₅)₂)₂

化学文摘社编号:

261733-18-0

分子量:

551.55

NACRES:

NA.22

PubChem Substance ID:

24884806

UNSPSC Code:

12352005

MDL number:

MFCD03788937

技术服务

需要帮助？我们经验丰富的科学家团队随时乐意为您服务。

让我们为您提供帮助

属性

Quality Segment

100

assay

97%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplings

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

256-262 °C

functional group

phosphine

greener alternative category

Aligned

storage temp.

2-8°C

SMILES string

N1c2cccc(P(c3ccccc3)c4ccccc4)c2Oc5c1cccc5P(c6ccccc6)c7ccccc7

InChI

1S/C36H27NOP2/c1-5-15-27(16-6-1)39(28-17-7-2-8-18-28)33-25-13-23-31-35(33)38-36-32(37-31)24-14-26-34(36)40(29-19-9-3-10-20-29)30-21-11-4-12-22-30/h1-26,37H

InChI key

HSWZLYXRAOXOLL-UHFFFAOYSA-N

说明

General description

We are committed to providing greener alternatives that adhere to the 12 Principles of Green Chemistry. This versatile phosphine ligand enables efficient transition metal-catalyzed cross-coupling reactions with enhanced selectivity and reduced byproduct formation, thus aligns with Green Chemistry principle "Catalysis". Click here for more information.

Application

N -XantPhos 是一种去质子化螯合芳基双膦配体，可用于：

制备 Pd-NiXantphos 催化系统，用于未活化的芳基氯化物的室温交叉偶联反应。
辛可宁铱 (Ⅲ) 环金属配合物的合成，该配合物具有良好的发光和量子效率。
N -XantPhos 和 N 修饰的对等物也用于氢甲酰化反应的铑基催化剂的制备。

存储类别

11 - Combustible Solids

怎么回事？

WGK 3

闪点 (F)

Not applicable

闪点 (°C)