666564
N -XantPhos
97%
别名:
安痛定, 4,6-双(二苯基膦)-10H-吩噁嗪, 4,6-双(二苯基膦)吩噁嗪
登录 查看组织和合同定价。
选择尺寸
关于此项目
线性分子式:
(C6H3)2NHO(P(C6H5)2)2
化学文摘社编号:
分子量:
551.55
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
InChI
1S/C36H27NOP2/c1-5-15-27(16-6-1)39(28-17-7-2-8-18-28)33-25-13-23-31-35(33)38-36-32(37-31)24-14-26-34(36)40(29-19-9-3-10-20-29)30-21-11-4-12-22-30/h1-26,37H
SMILES string
N1c2cccc(P(c3ccccc3)c4ccccc4)c2Oc5c1cccc5P(c6ccccc6)c7ccccc7
InChI key
HSWZLYXRAOXOLL-UHFFFAOYSA-N
assay
97%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplings
mp
256-262 °C
functional group
phosphine
storage temp.
2-8°C
Quality Level
Application
N -XantPhos 是一种去质子化螯合芳基双膦配体，可用于：
- 制备 Pd-NiXantphos 催化系统，用于未活化的芳基氯化物的室温交叉偶联反应。
- 辛可宁铱 (Ⅲ) 环金属配合物的合成，该配合物具有良好的发光和量子效率。
- N -XantPhos 和 N 修饰的对等物也用于氢甲酰化反应的铑基催化剂的制备。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Enhanced emission and analyte sensing by cinchonine iridium (III) cyclometalated complexes bearing bent diphosphine chelators.
Luo S X, et al.
Organometallics, 32(10), 2908-2917 (2013)
NiXantphos: A Deprotonatable Ligand for Room-Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides.
Zhang J, et al.
Journal of the American Chemical Society, 136(17), 6276-6287 (2014)
A new approach to dendritic supported NIXANTPHOS-based hydroformylation catalysts.
Ricken S, et al.
J. Mol. Catal. A: Chem., 257(1-2), 78-88 (2006)
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持