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671479

正丁基二(1-金刚烷基)膦

95%

greener alternative

更环保的选择

别名:

cataCXium® A

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选择规格

变更视图

关于此项目

经验公式(希尔记法):
C24H39P
化学文摘社编号:
分子量:
358.54
UNSPSC Code:
12352001
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
8726448
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product line

Buchwald Ligand

Quality Segment

assay

95%

reaction suitability

reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: C-C Bond Formation, reagent type: ligand
reaction type: Cross Couplings, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

functional group

phosphine

greener alternative category

SMILES string

CCCCP([C@]12C[C@H]3C[C@H](C[C@H](C3)C1)C2)[C@@]45C[C@@H]6C[C@@H](C[C@@H](C6)C4)C5

InChI

1S/C24H39P/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24/h17-22H,2-16H2,1H3/t17-,18+,19-,20-,21+,22-,23-,24-

InChI key

HTJWUNNIRKDDIV-FECFBMJZSA-N

General description

Solvias AG
配套销售
cataCXium® A通常用作交叉偶联反应的催化剂,如Suzuki和Sonogashira反应。
We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This ligand enables palladium-catalyzed cross-coupling of challenging, sterically hindered substrates under mild conditions. Its superior electronic and steric properties expand the scope of sustainable coupling transformations for pharmaceuticals. Click here for more information.

Application

cataCXium® A或二金刚烷基膦是一种体积庞大且富含电子的膦配体,对钯催化的交叉偶联反应非常有效,例如Heck 和 Suzuki偶联,Buchwald-Hartwig芳基氯化物胺化,和& # 945;酮的芳基化反应。

其他应用:
  • 钯催化的芳基和杂芳基卤化物的羰基化
  • 钯催化的(杂)芳腈的合成
  • 钯催化的芳基卤化物的氨基羰基化

Features and Benefits

  • 反应条件温和,
  • 催化剂负载量低,
  • 产率高,转化率高

Legal Information

US7148176
cataCXium is a registered trademark of Umicore AG & Co. KG


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存储类别

11 - Combustible Solids

闪点 (F)

Not applicable

闪点 (°C)

Not applicable

PPE(个人防护设备)

Eyeshields, Gloves, type N95 (US)



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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