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675938

Me 4 叔丁基磷

96%, solid

别名:

2-二叔丁基膦-3,4,5,6-四甲基-2′,4′,6′-三异丙基-1,1′-联苯, 四甲基二叔丁基磷, 四甲基叔丁基磷

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关于此项目

经验公式（希尔记法）:
C33H53P
化学文摘社编号:
857356-94-6
分子量:
480.75
UNSPSC Code:
12352002
PubChem Substance ID:
24885309
NACRES:
NA.22
MDL number:
MFCD09038436
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产品名称

Me 4 叔丁基磷, 96%

Quality Level

100

product line

Buchwald Ligand

assay

96%

form

solid

reaction suitability

reaction type: Cross Couplings, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: C-X Bond Formation

mp

168-172 °C

functional group

phosphine

SMILES string

CC1=C(C)C(C)=C(C)C(C(C(C(C)C)=CC(C(C)C)=C2)=C2C(C)C)=C1P(C(C)(C)C)C(C)(C)C

InChI

1S/C33H53P/c1-19(2)26-17-27(20(3)4)30(28(18-26)21(5)6)29-24(9)22(7)23(8)25(10)31(29)34(32(11,12)13)33(14,15)16/h17-21H,1-16H3

InChI key

RCRYEYMHBHPZQD-UHFFFAOYSA-N

Application

了解有关Buchwald 膦配体的更多信息。

Legal Information

用法以美国专利 6307087 和 6395916 为准。

存储类别

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCV9278
MKCS3056
MKCP5300
MKCP5194
MKCM0859

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商品

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Buchwald and coworkers develop versatile phosphine ligands for Pd-catalyzed C–N bond formation; enhancing synthetic reactions for 20 years.

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Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.

Buchwald Ligands

Buchwald and coworkers develop versatile phosphine ligands for Pd-catalyzed C–N bond formation; enhancing synthetic reactions for 20 years.

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Science (New York, N.Y.), 381(6661), 965-972 (2023-08-31)
Machine-learning methods have great potential to accelerate the identification of reaction conditions for chemical transformations. A tool that gives substrate-adaptive conditions for palladium (Pd)-catalyzed carbon-nitrogen (C-N) couplings is presented. The design and construction of this tool required the generation of
Huy Tran et al.
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A one-pot cascade sequence to generate synthetically challenging polycyclic scaffolds is reported utilizing a novel Lewis acid gold catalyst for the key cyclization step, enabling the divergent synthesis of both 6,6,5-tricyclic and 6,6,6,5-tetracyclic cores through both ligand and reaction condition
Takashi Ikawa et al.
Journal of the American Chemical Society, 129(43), 13001-13007 (2007-10-09)
We present results on the amidation of aryl halides and sulfonates utilizing a monodentate biaryl phosphine-Pd catalyst. Our results are in accord with a previous report that suggests that the formation of kappa(2)-amidate complexes is deleterious to the effectiveness of
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全球贸易项目编号

货号GTIN
675938-5G04061833338339
675938-250MG04061832747989
675938-1G04061826733462