682527
6-(二茂铁基)己硫醇
别名:
FHT, 6-(巯基己基)二茂铁
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关于此项目
经验公式(希尔记法):
C16H22FeS
化学文摘社编号:
分子量:
302.26
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
沸点
321-353 °C
质量水平
SMILES字符串
[Fe].[CH]1[CH][CH][CH][CH]1.SCCCCCC[C]2[CH][CH][CH][CH]2
InChI
1S/C11H17S.C5H5.Fe/c12-10-6-2-1-3-7-11-8-4-5-9-11;1-2-4-5-3-1;/h4-5,8-9,12H,1-3,6-7,10H2;1-5H;
InChI key
YENJERDZPAXYRX-UHFFFAOYSA-N
一般描述
6-(二茂铁基)己硫醇(FHT)是二茂铁基链烷硫醇,可形成自组装单层(SAM),其中二茂铁基键合可促进涂层与基底之间的电子交换。
应用
FHT可用作金基底上的SAM,作为电子传输介质,或能应用于生物电化学设备。FHT还可以形成金-硫醇键,官能化石墨烯涂层的金表面,用作电子转移介体。
这种材料的单分子层易于制造,并提供稳定和可重复的系统,并用于检测分子间的相互作用。
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Rebecca L Stiles et al.
Journal of the American Chemical Society, 130(6), 1856-1865 (2008-01-18)
Au nanoparticles fully coated with omega-ferrocenyl hexanethiolate ligands, with average composition Au225(omega-ferrocenyl hexanethiolate)43, exhibit a unique combination of adsorption properties on Pt electrodes. The adsorbed layer is so robust that electrodes bearing submonolayer, monolayer, and multilayer quantities of these nanoparticles
Damian J Matuszewski et al.
PloS one, 12(11), e0188496-e0188496 (2017-12-01)
The choice of an optimal feature detector-descriptor combination for image matching often depends on the application and the image type. In this paper, we propose the Log-Polar Magnitude feature descriptor-a rotation, scale, and illumination invariant descriptor that achieves comparable performance
Kinetic modulation of outer-sphere electron transfer reactions on graphene electrode with a sub-surface metal substrate.
Hui J, et al.
Electrochimica Acta, 211(1-2), 1016-1023 (2016)
Paul D Beer et al.
Chemical communications (Cambridge, England), (16), 1716-1717 (2002-08-29)
Surface pre-organisation within robust amidoferrocene self-assembled monolayers can be exploited in the selective electrochemical sensing of anions in both organic and aqueous media.
Creager, S.E.; Rowe, G.K.
Journal of Electroanalytical Chemistry (Lausanne Switzerland), 370, 203-203 (1994)
商品
Recent research highlights tunable properties of inorganic nanoparticles, driving interest in optoelectronics.
Self-assembled monolayers (SAMs) have diverse applications; article compares benefits of alkylthiolates on gold SAM systems.
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