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Merck
CN

683396

[Pd(allyl)Cl]2

greener alternative

≥98.0% (C, elemental analysis), solid, Umicore

别名:

氯化烯丙基钯(II)二聚体, \ [氯化钯(C3H5)] 2, \ [氯化钯（烯丙基）] 2, 二烯丙基二氯二钯, 双(η3-烯丙基)二(μ-氯)二钯(II), 双（烯丙基氯钯）, 双（烯丙基）二氯二钯, 双（烯丙基）二氯化钯, 烯丙基氯钯二聚体

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关于此项目

经验公式（希尔记法）:
C6H10Cl2Pd2
化学文摘社编号:
12012-95-2
分子量:
365.89
NACRES:
NA.22
PubChem Substance ID:
329760817
UNSPSC Code:
12161600
EC Number:
234-579-8
MDL number:
MFCD00044874
Beilstein/REAXYS Number:
4124623

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产品名称

[Pd(allyl)Cl]2, Umicore

SMILES string

Cl[Pd]CC=C.Cl[Pd]CC=C

InChI key

TWKVUTXHANJYGH-UHFFFAOYSA-L

InChI

1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2

assay

≥98.0% (C, elemental analysis)

form

solid

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

Quality Level

100

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

Aligned

storage temp.

2-8°C

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相关类别

Application

钯催化交叉偶联反应应用指南
[Pd(allyl)Cl]2 可用作催化剂：
  • 用于有机溴化物的硅烷基化。
  • 通过醛与芳基卤化物的偶联反应合成α-芳基羰基化合物。
  • 通过 C-H 官能化与芳基卤化物进行交叉偶联反应制备各种芳基噻吩衍生物。

Legal Information

Umicore 产品

更多信息参见www.pmc.umicore.com

Other Notes

用于不对称和交叉偶联催化的 Umicore 预催化剂

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315

Hazard Classifications

Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCN2938
BCCM1566
BCCK5039
BCCG7046
BCCH3382

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Direct Arylation of Thiophenes via Palladium-Catalysed C-H Functionalisation at Low Catalyst Loadings
Battace A, et al.
Advanced Synthesis & Catalysis, 349(16), 2507-2516 (2007)
Synthesis of HOMSi Reagents by Pd/Cu-Catalyzed Silylation of Bromoarenes with Disilanes
Minami Y, et al.
Chemistry Letters (Jpn), 43(2), 201-203 (2014)
Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos
Giang D Vo and John F Hartwig
Angewandte Chemie (International ed. in English), 2127-2130 (2008)
Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos
Giang D Vo and John F Hartwig
Angewandte Chemie (International Edition in English), 2127-2130 (2008)
Direct Arylation of Thiophenes via Palladium-Catalysed C-H Functionalisation at Low Catalyst Loadings
Battace A, et al.
advanced synthesis and catalysis, 349(16), 2507-2516 (2007)

商品

Palladium-catalyzed Cross-coupling Reactions

A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

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