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683396

[Pd(allyl)Cl]2

greener alternative

≥98.0% (C, elemental analysis), solid, Umicore

别名:

氯化烯丙基钯(II)二聚体, \ [氯化钯(C3H5)] 2, \ [氯化钯（烯丙基）] 2, 二烯丙基二氯二钯, 双(η3-烯丙基)二(μ-氯)二钯(II), 双（烯丙基氯钯）, 双（烯丙基）二氯二钯, 双（烯丙基）二氯化钯, 烯丙基氯钯二聚体

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关于此项目

经验公式（希尔记法）:
C6H10Cl2Pd2
化学文摘社编号:
12012-95-2
分子量:
365.89
NACRES:
NA.22
PubChem Substance ID:
329760817
UNSPSC Code:
12161600
EC Number:
234-579-8
Beilstein/REAXYS Number:
4124623
MDL number:
MFCD00044874
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产品名称

[Pd(allyl)Cl]2, Umicore

Quality Level

100

assay

≥98.0% (C, elemental analysis)

form

solid

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

Aligned

storage temp.

2-8°C

SMILES string

Cl[Pd]CC=C.Cl[Pd]CC=C

InChI

1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2

InChI key

TWKVUTXHANJYGH-UHFFFAOYSA-L

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

[Pd(allyl)Cl]2 可用作催化剂：
  • 用于有机溴化物的硅烷基化。
  • 通过醛与芳基卤化物的偶联反应合成α-芳基羰基化合物。
  • 通过 C-H 官能化与芳基卤化物进行交叉偶联反应制备各种芳基噻吩衍生物。

钯催化交叉偶联反应应用指南

Other Notes

用于不对称和交叉偶联催化的 Umicore 预催化剂

Legal Information

Umicore 产品

更多信息参见www.pmc.umicore.com

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315

Hazard Classifications

Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCN2938
BCCM1566
BCCK5039
BCCG7046
BCCH3382

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商品

Palladium-catalyzed Cross-coupling Reactions

A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos
Giang D Vo and John F Hartwig
Angewandte Chemie (International ed. in English), 2127-2130 (2008)
Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos
Giang D Vo and John F Hartwig
Angewandte Chemie (International Edition in English), 2127-2130 (2008)
Direct Arylation of Thiophenes via Palladium-Catalysed C-H Functionalisation at Low Catalyst Loadings
Battace A, et al.
advanced synthesis and catalysis, 349(16), 2507-2516 (2007)
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全球贸易项目编号

货号GTIN
683396-5G04061832755731
683396-500MG04061832755724