691674
2-二环己基膦-2′,4′,6′-三异丙基联苯金(I) 双(三氟甲烷磺酰)亚胺
powder
别名:
XPhos AuNTf2
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关于此项目
经验公式（希尔记法）:
C35H49AuF6NO4PS2
化学文摘社编号:
分子量:
953.83
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
2-二环己基膦-2′,4′,6′-三异丙基联苯金(I) 双(三氟甲烷磺酰)亚胺,
form
powder
Quality Level
reaction suitability
core: gold, reagent type: catalyst
SMILES string
FC(F)(F)S(=O)(=O)N([Au])S(=O)(=O)C(F)(F)F.CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2ccccc2P(C3CCCCC3)C4CCCCC4
InChI
1S/C33H49P.C2F6NO4S2.Au/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3;;/q;-1;+1
InChI key
GMVGZINKTXAKDT-UHFFFAOYSA-N
Application
Gold Catalysts — 21st Century ′Gold Rush′
- Catalyst for isomerization of allenyl carbinol esters, hydroxy- and methoxycyclization, cycloisomerisation of diynes
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
商品
Access gold precatalysts, silver salts, and unsaturated building blocks to accelerate research success in catalysis applications.
An unusual access to medium sized cycloalkynes by a new gold(I)-catalysed cycloisomerisation of diynes.
Yann Odabachian et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(36), 8966-8970 (2009-08-04)
Andrea K Buzas et al.
Organic letters, 9(6), 985-988 (2007-02-14)
A study concerning the gold(I)-catalyzed rearrangement of diversely substituted allenyl carbinol esters into functionalized 1,3-butadien-2-ol esters is described. The mild conditions employed allow the efficient, rapid, and stereoselective synthesis of a variety of such compounds via a new 1,3-shift of
Gold(I)-catalyzed 5-endo hydroxy- and alkoxycyclization of 1,5-enynes: efficient access to functionalized cyclopentenes.
Andrea K Buzas et al.
Angewandte Chemie (International ed. in English), 46(7), 1141-1144 (2006-12-14)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 691674-1G | 04061826733943 |
| 691674-250MG | 04061833550571 |