691674
2-二环己基膦-2′,4′,6′-三异丙基联苯金(I) 双(三氟甲烷磺酰)亚胺
powder
可持续性特点
别名:
XPhos AuNTf2
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关于此项目
经验公式（希尔记法）:
C35H49AuF6NO4PS2
化学文摘社编号:
分子量:
953.83
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
2-二环己基膦-2′,4′,6′-三异丙基联苯金(I) 双(三氟甲烷磺酰)亚胺,
form
powder
Quality Segment
reaction suitability
core: gold, reagent type: catalyst
sustainability
Sustainability features
SMILES string
FC(F)(F)S(=O)(=O)N([Au])S(=O)(=O)C(F)(F)F.CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2ccccc2P(C3CCCCC3)C4CCCCC4
InChI
1S/C33H49P.C2F6NO4S2.Au/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3;;/q;-1;+1
InChI key
GMVGZINKTXAKDT-UHFFFAOYSA-N
General description
This productaligns with the Green Chemistry Principle of Catalysis. It is a bulky phosphine ligand for palladium catalysis, excellent for challenging cross-coupling reactions with sterically hindered substrates due to its large cone angle. Click here for more information.
Application
Gold Catalysts — 21st Century ′Gold Rush′
- Catalyst for isomerization of allenyl carbinol esters, hydroxy- and methoxycyclization, cycloisomerisation of diynes
警示词
Warning
危险代码
Hazard Classifications
Eye Irrit. 2 - STOT SE 3
靶器官
Respiratory system
存储类别
13 - Non Combustible Solids
WGK
WGK 3
闪点 (F)
Not applicable
闪点 (°C)
Not applicable
PPE（个人防护设备）
dust mask type N95 (US), Eyeshields, Gloves