695211
2-二叔丁基膦-2′-甲基联苯
solid
别名:
tBuMePhos
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选择尺寸
关于此项目
经验公式（希尔记法）:
C21H29P
化学文摘社编号:
分子量:
312.43
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
2-二叔丁基膦-2′-甲基联苯,
SMILES string
Cc1ccccc1-c2ccccc2P(C(C)(C)C)C(C)(C)C
InChI
1S/C21H29P/c1-16-12-8-9-13-17(16)18-14-10-11-15-19(18)22(20(2,3)4)21(5,6)7/h8-15H,1-7H3
InChI key
UJONYAVMBYXBJQ-UHFFFAOYSA-N
form
solid
reaction suitability
reagent type: ligand
reaction type: Arylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Reductions
mp
90-95 °C
functional group
phosphine
Quality Level
Legal Information
用法以美国专利 6307087 和 6395916 为准。
Application
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
David S Surry et al.
Angewandte Chemie (International ed. in English), 47(34), 6338-6361 (2008-07-30)
Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context. This Review discusses
Ruben Martin et al.
Accounts of chemical research, 41(11), 1461-1473 (2008-07-16)
The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Recently, Pd-catalyzed carbon-carbon
David S Surry et al.
Chemical science, 2(1), 27-50 (2011-01-01)
Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand
商品
Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.
Buchwald phosphine ligands for C-C, C-N, and C-O bond formation.
相关内容
Buchwald Portfolio: Palladacycles and Ligands
Phosphine Ligand Application Guide
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